研究目的
To investigate the adsorption and photocatalytic decomposition ability of TiO2-coated porous glass cloth composites for eliminating volatile organic compounds (VOCs) such as 2-propanol at low concentrations, and to understand the effects of temperature and water content on these processes.
研究成果
The TiO2-coated porous glass cloth composite demonstrated high adsorption and photocatalytic decomposition abilities for gaseous 2-propanol, effectively reducing VOC concentrations and minimizing intermediate emissions. Temperature and water content influenced the decomposition rates, with higher temperatures accelerating diffusion and water content affecting adsorption competition. The composite is a promising candidate for practical air purification applications.
研究不足
The TiO2 coating was inhomogeneous due to the high fiber density of the cloth, which may affect photocatalytic efficiency. The study focused on 2-propanol and may not generalize to all VOCs. The mechanisms of crack generation and TiO2 loading variations with leaching time require further investigation.
1:Experimental Design and Method Selection:
The study involved preparing TiO2 and porous glass cloth composites by acid leaching E-glass cloth followed by TiO2 dip-coating. The adsorption and photocatalytic decomposition of gaseous 2-propanol were evaluated under controlled conditions of temperature and humidity.
2:Sample Selection and Data Sources:
E-glass cloth was used as the base material, with samples prepared by varying acid leaching times (
3:5 to 12 hours) and TiO2 coating. Gaseous 2-propanol at 300 ppm concentration was used as the VOC. List of Experimental Equipment and Materials:
Equipment included FE-SEM for microstructure analysis, XRD for crystalline phase identification, XRF for chemical composition, N2 adsorption analyzers for surface area measurement, and gas chromatography for concentration measurements. Materials included E-glass cloth, TiO2 suspension, HCl, ethanol, 2-propanol, and sodium carbonate.
4:Experimental Procedures and Operational Workflow:
Acid leaching was performed in HCl solution at 40°C for specified times, followed by washing, drying, and TiO2 dip-coating. Samples were characterized using various techniques. Adsorption and photocatalytic experiments were conducted in sealed vials under dark and UV light conditions, with concentrations monitored over time.
5:Data Analysis Methods:
Specific surface areas were calculated using BET method, pore-size distributions estimated by Saito-Foley fitting, and photocatalytic decomposition rates analyzed based on concentration changes of 2-propanol, acetone, and CO2.
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FE-SEM
Hitachi S-2400, S-5200
Hitachi High-Technologies
Used for observing the microstructure of the glass fibers and TiO2 coatings.
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XRD
MiniFlex 600
Rigaku Co.
Used for identifying the crystalline phase of TiO2.
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XRF
ZSX Primus μ
Rigaku Co.
Used for analyzing the chemical composition of the samples.
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Gas chromatograph
GC-8A
Shimadzu Co.
Used for measuring concentrations of 2-propanol, acetone, and CO2 during adsorption and photocatalytic experiments.
GC-8A Series Gas Chromatograph
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E-glass cloth
Arisawa Manufacturing Co. Ltd.
Used as the base material for preparing porous glass cloth by acid leaching and as a support for TiO2 coating.
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TiO2 suspension
TKD-701
TAYCA Co.
Used for dip-coating to apply TiO2 photocatalyst onto the glass cloth.
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N2 adsorption analyzer
BELLSOAP mini II, BELSORP-max-N-VP-CM
BEL Japan Inc.
Used for measuring N2 adsorption isotherms to determine specific surface areas and pore-size distributions.
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BL lamp
FL15BLB
Toshiba Lighting & Technology Co.
Used as the UV light source for photocatalytic decomposition experiments.
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Calibration gas generator
Permeater PD-1B
GASTECH Co.
Used for generating air-diluted 2-propanol vapor.
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Gas detector tube
No.6
GASTEC Co.
Used for confirming water content in the mixed gas.
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