研究目的
To investigate the use of strained bubbles in van der Waals heterostructures as local emitters of photoluminescence with adjustable wavelength, focusing on strain engineering and exciton funneling effects.
研究成果
Strained bubbles in van der Waals heterostructures provide a reliable method for localized, tunable photoluminescence with enhanced intensity due to exciton funneling. The PL energy shift correlates with strain, and substrate choice enables control over emission characteristics. This approach offers a pathway for creating artificial atoms for optoelectronic applications.
研究不足
The study is limited to specific monolayer TMDCs and substrates; bubble sizes vary by substrate, affecting PL measurements. The exciton drift length may be shorter than bubble radius, reducing funneling efficiency. Quenching mechanisms are complex and not fully elucidated for all substrates.
1:Experimental Design and Method Selection:
The study utilized hydrocarbon-filled bubbles formed in van der Waals heterostructures by depositing monolayer TMDCs on atomically flat substrates. The strain distribution and PL characteristics were analyzed using atomic force microscopy (AFM) and photoluminescence spectroscopy.
2:Sample Selection and Data Sources:
Monolayer MoS2 flakes were deposited on various substrates including hBN, graphene, graphite, PtSe2, WS2, and bulk MoS
3:Samples were prepared using a wet-transfer technique and annealed to form bubbles. List of Experimental Equipment and Materials:
Equipment included a Horiba Raman system XploRATM PLUS for PL measurements, AFM for topography, and materials such as poly(methyl-methacrylate) (PMMA) for transfer.
4:Experimental Procedures and Operational Workflow:
Heterostructures were fabricated, annealed, and characterized. PL spectra were measured at room temperature with specific laser energies and spot sizes. AFM was used to map bubble distribution and geometry.
5:Data Analysis Methods:
PL peak positions were identified using Gauss-Lorentz fitting in LabSpec6 software. Strain was correlated with PL shifts and intensities, and optical interference effects were analyzed using Fresnel theory.
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