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Strained bubbles in van der Waals heterostructures as local emitters of photoluminescence with adjustable wavelength

DOI:10.1021/acsphotonics.8b01497 期刊:ACS Photonics 出版年份:2019 更新时间:2025-09-19 17:15:36
摘要: The possibility to tailor photoluminescence (PL) of monolayer transition metal dichalcogenides (TMDCs) using external factors such as strain, doping and external environment is of significant interest for optoelectronic applications. Strain in particular can be exploited as a means to continuously vary the bandgap. Micrometer-scale strain gradients were proposed for creating ‘artificial atoms’ that can utilize the so-called exciton funneling effect and work, for example, as exciton condensers. Here we describe room-temperature PL emitters that naturally occur whenever monolayer TMDC is deposited on an atomically flat substrate. These are hydrocarbon-filled bubbles which provide predictable, localized PL from well-separated submicron areas. Their emission energy is determined by the built-in strain controlled only by the substrate material, such that both the maximum strain and the strain profile are universal for all bubbles on a given substrate, i.e., independent of the bubble size. We show that for bubbles formed by monolayer MoS2, PL can be tuned between 1.72 to 1.81 eV by choosing bulk PtSe2, WS2, MoS2 or graphite as a substrate and its intensity is strongly enhanced by the funneling effect. Strong substrate-dependent quenching of the PL in areas of good contact between MoS2 and the substrate ensures localization of the luminescence to bubbles only; by employing optical reflectivity measurements we identify the mechanisms responsible for the quenching. Given the variety of available monolayer TMDCs and atomically flat substrates and the ease of creating such bubbles, our findings open a venue for making and studying the discussed light-emitting ‘artificial atoms’ that could be used in applications.
作者: Anastasia V. Tyurnina,Denis A. Bandurin,Ekaterina Khestanova,Vasyl G. Kravets,Maciej Koperski,Francisco Guinea,Alexander N. Grigorenko,Andre K. Geim,Irina V. Grigorieva
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To investigate the use of strained bubbles in van der Waals heterostructures as local emitters of photoluminescence with adjustable wavelength, focusing on strain engineering and exciton funneling effects.

Strained bubbles in van der Waals heterostructures provide a reliable method for localized, tunable photoluminescence with enhanced intensity due to exciton funneling. The PL energy shift correlates with strain, and substrate choice enables control over emission characteristics. This approach offers a pathway for creating artificial atoms for optoelectronic applications.

The study is limited to specific monolayer TMDCs and substrates; bubble sizes vary by substrate, affecting PL measurements. The exciton drift length may be shorter than bubble radius, reducing funneling efficiency. Quenching mechanisms are complex and not fully elucidated for all substrates.

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