研究目的
To analyze the laws found from studying structure and phase evolution in the surface layer of SiC ceramic treated with an intense pulsed electron beam.
研究成果
Irradiation of SiC ceramic with an intense pulsed electron beam leads to changes in polymorphic composition, surface fragmentation, nanostructuring, and increased hardness and Young's modulus, attributed to thermomechanical stresses from rapid heating and cooling. This enhances material properties for practical applications.
研究不足
The study is limited to specific electron-beam parameters and SiC ceramic compositions; results may not generalize to other materials or conditions. Potential optimizations include varying pulse numbers or energy densities further.
1:Experimental Design and Method Selection:
The study involved irradiating SiC ceramic samples with an intense pulsed electron beam to investigate changes in elemental and phase compositions and substructure. The methodology included using specific electron-beam parameters (accelerated electron potential 18 keV, energy densities of 10, 15, and 20 J/cm2, pulse length 200 μs, three pulses) to modify the surface layer.
2:Sample Selection and Data Sources:
Ceramic samples were prepared using SiC powder (particle size 0.9–4.0 μm) and nanopowder (particle size 0.06 μm), supplemented with 3 mass% SiC nanopowder (NEOMAT, specific surface area 32 m2/g). Samples were tablets (14 mm diameter, 3 mm thick) produced via SPS sputtering (SPS 155 system, SPSSYNNEX) at T_sp = 2100°C, P_press = 70 MPa, τ_sp = 10 min, then ground and polished.
3:9–0 μm) and nanopowder (particle size 06 μm), supplemented with 3 mass% SiC nanopowder (NEOMAT, specific surface area 32 m2/g). Samples were tablets (14 mm diameter, 3 mm thick) produced via SPS sputtering (SPS 155 system, SPSSYNNEX) at T_sp = 2100°C, P_press = 70 MPa, τ_sp = 10 min, then ground and polished. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Equipment included the SOLO system (IHCE SB RAS) for electron-beam treatment, JEOL SEM-7500FA scanning electron microscope, Shimadzu XRD-7000 diffractometer, JEM 2100F transmission electron microscope (JEOL), and Shimadzu DUH-211S dynamic ultramicro hardness tester with Berkovich diamond pyramid.
4:Experimental Procedures and Operational Workflow:
Samples were irradiated with the electron beam under specified parameters. Structure and phase compositions were analyzed before and after treatment using SEM, XRD, and TEM. Physicomechanical characteristics were measured via nanoindentation at P = 10 g load.
5:Data Analysis Methods:
X-ray diffraction for phase composition analysis, electron microscopy for structural and morphological studies, and nanoindentation for hardness and Young's modulus measurements.
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Scanning Electron Microscope
SEM-7500FA
JEOL
Used for analyzing the structure and morphology of the ceramic surface layer.
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X-ray Diffractometer
XRD-7000
Shimadzu
Used for phase composition analysis of the ceramic.
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Transmission Electron Microscope
JEM 2100F
JEOL
Used for studying the morphology and defect substructure of thin foils of the ceramic.
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Dynamic Ultramicro Hardness Tester
DUH-211S
Shimadzu
Used for measuring physicomechanical characteristics via nanoindentation.
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SOLO system
SOLO
IHCE SB RAS
Used for intense pulsed electron beam treatment of the ceramic surface layer.
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SPS System
SPS 155
SPSSYNNEX
Used for spark plasma sintering to prepare ceramic samples.
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SiC Nanopowder
NEOMAT
NEOMAT
Used as a supplement in the powder base for sample preparation.
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