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- 摘要
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- 实验方案
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Cation Exchange as a Mechanism to Engineer Polarity in Layered Perovskites.
摘要： Cation exchange reactions performed on the n = 2 Dion-Jacobson phases RbNdNb2O7 and RbNdTa2O7, using LiNO3 and NaNO3, yield the corresponding LiNdM2O7 and NaNdM2O7 (M = Nb, Ta) phases. Synchrotron X-ray and neutron powder diffraction data, in combination with second-harmonic generation data and supported by first-principles DFT calculations, reveal that the LiNdM2O7 phases adopt n = 2 Ruddlesden-Popper type structures with an aˉaˉc+/-(aˉaˉc+) distortion described in the polar space group B2cm. In contrast, the NaNdM2O7 phases adopt n = 2 Ruddlesden-Popper type structures with an aˉb0c0/b0aˉc0 distortion, described in the centrosymmetric space group P42/mnm. The differing structures adopted by the LiNdM2O7 and NaNdM2O7 phases are rationalized on the basis of a competition between i) optimizing the size of the Li/Na coordination site via octahedral tilting and ii) ordering the Na/Li cations within the (Li/Na)O2 sheets to minimize cation-cation repulsion – the former appears to be the dominant factor for the Li phases and the latter factor dominates for the Na phases. The strong A’-cation dependence of the tilting distortions adopted by the A’NdM2O7 phases suggests that by careful selection of the substituting cation the tilting distortions of layered perovskite phases can be rationally tuned to adopt polar configurations, and thus new ferroelectric phases can be synthesized.
关键词： Layered perovskites,Cation exchange,Structural distortion,Ferroelectric materials,Polarity engineering
更新于2025-09-23 15:21:01
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The application of compound proportional resonant control strategy in multiple PV inverters system
摘要： In order to eliminate the effect on the grid current caused by the background harmonic voltage and the reference signal on the grid connected multi-inverter, this paper adopts the double closed-loop feed-forward control strategy. This strategy is based on the inductor voltage and the grid-connected current, and the integrated control strategy of quasi-proportional resonance loop parallel to a specific harmonic compensation loop. Based on the closed-loop model of multiple inverters, the change curves of the transfer function of the two control strategies are compared with the feed-forward control and the composite proportional resonance. The two corresponding control methods are used to analyze the current quality of the multi-inverter impact. Finally, the MATLAB/Simulink simulation model is set up to verify the proposed control strategies. The simulation results show that the proposed method can achieve better tracking of the sinusoidal command signal at the fundamental frequency, and enhance the anti-interference ability of the system at the 3rd, 5th, and 7th harmonic frequency.
关键词： compound proportional resonant control,Grid-connected multi-inverter,background harmonics,total harmonic distortion (THD),feed-forward control
更新于2025-09-23 15:21:01
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[IEEE 2019 IEEE 26th International Symposium on the Physical and Failure Analysis of Integrated Circuits (IPFA) - Hangzhou, China (2019.7.2-2019.7.5)] 2019 IEEE 26th International Symposium on Physical and Failure Analysis of Integrated Circuits (IPFA) - Characterization of 1122nm Laser for Laser Based Fault Isolation Applications
摘要： This paper presents one of the first studies of the harmonic impact of a significantly large photovoltaic (PV) solar farm of 20 MW in a utility distribution system. This solar farm is a constituent of the 80-MW PV solar farm in Sarnia, Ontario, which is so far the largest solar farm in Canada. The utility network is modeled in detail using the commercial grade PSCAD/EMTDC software, which is validated through load flow studies conducted by CYME software and correlated with SCADA measurements. The validated network model is used for network resonance study and harmonics impact analysis of the solar farms under different network conditions. The harmonics data instrumented for several months were provided by the transmission utility at the two solar farm units and at the main feeder substation. These data were utilized for extensive harmonic impact studies with widely different short-circuit levels and network resonance conditions. This paper presents the detailed procedure adopted for performing such harmonic impact studies. It is concluded that this large solar farm may not cause any substantial voltage distortion on the distribution network during steady-state operating conditions. However, recommendations are made for utilities to perform such studies to ensure the safe operation of critical loads.
关键词： network resonance,total harmonic distortion,solar energy,harmonics,Distribution systems,total demand distortion,photovoltaic (PV) solar system,frequency scan
更新于2025-09-23 15:19:57
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Distortion and Dilution Behavior for Laser Metal Deposition onto Thin Sheet Metals
摘要： The combination of additive manufacturing and incremental sheet forming offers great flexibility in the manufacture of function-integrated parts. In this study, both processes were carried out by the same CNC machine. This offers the possibility to manufacture large-scale lightweight parts with smaller additive parts on it in one machine and clamping device. Additionally, the process combination can lead to a reduced energy and material consumption for small batch sizes. DC01 sheets are used as a substrate with two different initial conditions. The first condition is as delivered steel sheet and the second is an incrementally formed with a thickness of 0.5 mm. The additive manufacturing was conducted by laser metal deposition (LMD). The powder material is a stainless steel 316 L. A segmentation of the cladding surface was applied and the path strategy of the laser movement was varied simultaneously to analyse the warpage of the thin substrate. It is shown that there is a dependency between the build-up strategies and the melt pool temperature, the thermal distortion, the dilution and the size of the cladding area. A segmentation of the working surface causes a lower melt pool temperature and thermal distortion. The lower melt pool temperature also generates a reduced dilution zone.
关键词： Thermal distortion,Laser metal deposition,Incremental sheet forming,Stainless steel
更新于2025-09-23 15:19:57
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Numerical studies of residual states and scaling effects in laser-directed energy deposition additive manufacturing
摘要： Sequentially coupled thermo-mechanical model was used to simulate the residual stresses and residual distortions in the directed energy deposition additive manufacturing by laser. The proposed models were validated by comparison with experimental data. Different sizes of components were used to study the scaling effects. Results indicate that the residual stress can be controlled by the component sizes. This phenomenon can be explained by the bending deformation and the temperature fluctuations, especially the cooling rate, in the directed energy deposition additive manufacturing process. Both the bending deformation and the temperature fluctuations can be controlled by the ambient temperature and the designed process parameters. Analytical model was established to show how the components’ sizes affect the final residual states in combination with different design parameters.
关键词： Scaling effect,Residual stress,Residual distortion,Additive manufacturing
更新于2025-09-23 15:19:57
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Tracing harmonic distortion and voltage unbalance in secondary radial distribution networks with photovoltaic uncertainties by an iterative multiphase harmonic load flow
摘要： Secondary radial distribution networks (SRDNs) have been increasingly affected by the uncertainties of harmonic sources associated with photovoltaic (PV) systems. The quantitative assessment of uncertainty propagation causing harmonic distortion and voltage unbalance can be successively handled by probabilistic or affine formulations of harmonic load flows (HLFs). This study developed a general analytical technique (GAT) for solving iterative multiphase HLFs in SRDNs with PV uncertainties. This technique merges the point-estimate method (PEM) and complex affine arithmetic (AA), combined with Legendre series approximation (LGSA). It also models the input correlation. One advantage of this GAT is that the iterative harmonic penetration (IHP) method, modeled for HLF, accounts for the interaction of background harmonic voltage with the PV harmonic current. The first prerequisite was evidently an uncertainty model for PV harmonic current. This paper presents the results for a real unbalanced three-phase SRDN and compares them with those obtained with the Monte-Carlo simulation (MCS). These confirmed the accuracy of GAT as well as its lower computational cost. The numerical results obtained showed that the GAT outperformed the incomplete GAT (IGAT), which is solely based on PEM and Cornish-Fisher expansion, thanks to the ability of AA to bound the outputs used in the LGSA.
关键词： PV system,Unbalance,Complex affine arithmetic,Harmonic load flow,Harmonic distortion,Point estimate methods
更新于2025-09-23 15:19:57
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Predictive Model for Thermal and Stress Field in Selective Laser Melting Processa??Part I
摘要： During the part forming in laser powder bed fusion process, thermal distortion is one big problem due to the thermal stress which is caused by the high cooling rate and temperature gradient. Therefore, it is important to know the effect of process parameters on thermal and stress evolution in the melt zone. In this paper, a 3D finite element model for Selective Laser Melting (SLM) process based on sequentially coupled thermo-mechanical field analysis was developed for accurately predicting thermal history and surface features, like distortion and residual stress. Temperature dependent material properties for performed material 304L stainless steel are incorporated into the model capturing the change from powder to fully dense solid stainless steel. Surface temperature gradients and thermal stress were fully presented in the development of different parameter sets, which designed for the probability of reducing defect formation. Simulation results showed that the sequent thermal cyclic melting in successive scanned tracks resulted in alternating compressive and tensile thermal stresses. A predictive model for thermal and stress field in large part by selective laser melting process is come up in Part II. After the parts cooled down to room temperature, higher residual stresses were found in longitudinal stress. This paper will provide guidance on how to achieve minimum residual stresses and deformations by the study of the process parameters.
关键词： finite element analysis,SLM,distortion,residual stress
更新于2025-09-23 15:19:57
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Predictive Model for Thermal and Stress Field in Selective Laser Melting Processa??Part II
摘要： Finite Element Analysis (FEA) is used to predict the transient thermal cycle and optimize process parameters to analyze these effects on deformation and residual stresses. However, the process of predicting the thermal history in this process with the FEA method is usually time-consuming, especially for large-scale parts. In this paper, an effective predictive model of part deformation and residual stress was developed for accurately predicting deformation and residual stresses in large-scale parts. An equivalent body heat flux proposed from the single layer laser scan model was imported as the thermal load to the layer by layer model. The hatched layer is then heated up by the equivalent body heat flux and used as a basic unit element to build up the macroscale part. The thermal history and residual stress fields of two solid parts with different support structures during the SLM process were simulated. Layer heat source method has the capability for fast temperature prediction in the SLM process, while sacrificing modeling details for the computational time-saving purpose. Thus numerical modeling in this work can be a very useful tool for the parametric study of process parameters, residual stresses and deformations.
关键词： distortion,finite element analysis,residual stress,layer heat source model,SLM
更新于2025-09-23 15:19:57
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[IEEE 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Chicago, IL, USA (2019.6.16-2019.6.21)] 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Precursor reaction method with high Ga Cu(In,Ga)(S,Se) <sub/>2</sub> to achieve increased open-circuit voltage
摘要： Direct detection transceivers offer advantages, including low cost and complexity, in short- and medium-haul links. We carried out studies seeking to identify the signal formats which offer the highest information spectral densities and maximum transmission distances for direct detection links. The performance of two spectrally efficient optical signal formats, single-sideband (SSB) Nyquist pulse-shaped subcarrier modulation (SCM) and SSB orthogonal frequency-division multiplexing (OFDM), are compared by means of simulations. The comparison is performed for a range of wavelength-division multiplexing (WDM) net information spectral densities up to 2.0 b/s/Hz by varying the signal bandwidth, modulation cardinality, and WDM channel spacing. The signal formats’ tolerance to signal–signal beating interference, resulting from square-law detection, is investigated, and the Nyquist-SCM format is found to suffer lower penalties from this nonlinearity at high information spectral densities. In 7 × 28 Gb/s WDM transmission at 2.0 b/s/Hz (with electronic pre-distortion and EDFA-only amplification), Nyquist-SCM signals can be transmitted over distances of up to 720 km of standard SMF in comparison to a maximum of 320 km with the OFDM signal format.
关键词： Digital signal processing,direct detection,wavelength division multiplexing,subcarrier modulation,electronic pre-distortion,optical communication,Nyquist pulse shaping,signal–signal beating interference,orthogonal frequency division multiplexing
更新于2025-09-23 15:19:57
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[IEEE 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Chicago, IL, USA (2019.6.16-2019.6.21)] 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - New designed electrode patterns on rear side of bifacial PERC solar cells
摘要： Present-day smartphones and tablets demand high audio fidelity (e.g., total harmonic distortion + noise, THD + N < 0.01%), and high noise immunity (e.g., power supply rejection ratio, PSRR > 80 dB) to allow high integration in an SoC. The design of conventional closed-loop pulse width modulation (PWM) Class-D amplifiers (CDAs) typically involves undesirable trade-offs between fidelity (qualified by THD + N), PSRR and switching frequency. In this paper, we propose a fully integrated CMOS CDA that embodies a novel input-modulated carrier generator and a novel phase-error-free PWM modulator, collectively allowing the employment of high loop-gain to achieve high PSRR, yet without compromising linearity/dynamic-range or resorting to high switching frequency. The prototype CDA, realized in 65 nm CMOS, achieves a THD + N of 0.0027% and a power efficiency of 94% when delivering 500 mW to an 8 ? load from VDD = 3.6 V. The PSRR of the prototype CDA is very high, –101 dB @217 Hz and 90 dB @1 kHz, arguably the highest to-date. Furthermore, the switching frequency of the prototype CDA varies from 320 to 420 kHz, potentially reducing the EMI due to spread-spectrum. In addition, the prototype CDA is versatile with a large operating-voltage range, with VDD ranging from rechargeable 1.2 V single battery to standard 3.6 V smart-device supply voltages.
关键词： Audio power amplifiers,power supply rejection ratio (PSRR),total harmonic distortion (THD),pulse width modulation (PWM),class D amplifiers
更新于2025-09-23 15:19:57