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Boron doped carbon dots as a multifunctional fluorescent probe for sorbate and vitamin B12
摘要： Boron doped carbon dots (B-CD) were synthesized by a one-step hydrothermal method using phenylboronic acid as the starting material. They have an average size of about 3.3 nm, with excitation/emission wavelength of 247/323 nm and a quantum yield of 12%. The B-CD is shown to be viable fluorescent probe for sorbate (PS) and vitamin B12 (VB12). The fluorescence (FL) of the B-CD is quenched in the presence of PS or VB12 mainly coming from inner filter effect (IFE), but F?rster resonance energy transfer (FRET) from the B-CD (as a donor) to PS/VB12 (as an acceptor) cannot be excluded. The probe enables PS to be detected by fluorometry with a linear response in the 0.20–24 μM concentration range and a 6.1 nM detection limit (at 3σ/slope). For VB12, the data are 0.20–30 μM and 8.0 nM.
关键词： Fluorescent probe,Sorbic acid,Fluorescence quenching ratios,Intra-day precision,Selectivity,Inter-day precision,Quenching mechanism,Real sample analysis
更新于2025-09-23 15:23:52
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VO2 microrods synthesized from V2O5 thin films
摘要： Self-assembled single crystal VO2 microrods (MRs) with a length up to 600 μm have been synthesized on Si and sapphire substrates by the annealing of V2O5 thin films. The nucleation and growth of VO2 MRs from V2O5 thin films were investigated. The morphology and microstructure evolutions of the intermediate phases during the reduction process were characterized by SEM, HRTEM, XPEEM, and Raman spectroscopy. The results have shown that the conversion of V2O5 thin films to VO2 MRs is dominated by a melting-nucleation-growth mechanism. The growth of VO2 MRs can be controlled by V2O5 melting process and a consistent feeding of V2O5 liquids to the growing VO2 MR would lead to ultra-long VO2 MRs. Further, epitaxial growth of VO2 MRs can be induced by using an r-cut sapphire substrate.
关键词： Growth mechanism,Reduction,V2O5 thin films,VO2 microrods,Epitaxial growth
更新于2025-09-23 15:23:52
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Optimizing P25-rGO composites for pesticides degradation: Elucidation of photo-mechanism
摘要： The junction of graphene oxide with TiO2 particles can help develop more efficient photocatalysts capable to harvest radiation in a wider range of the electromagnetic spectrum for real photocatalytic applications. The synthesis procedure of TiO2 P25-rGO composites was optimized to photodegrade a selected mixture of pesticides classified by EU as priority pollutants (alachlor, diuron, atrazine and isoproturon). The influence of temperature and time of hydrothermal method, as well as the effect of graphene oxide (GO) percentage added in the synthesis, was studied to obtain the nanocomposite that showed the highest photoactivity. Long time and moderate temperature have offered the best interaction between TiO2 P25 and rGO. GO was quantitatively reduced to rGO during the hydrothermal treatment, but maintains a higher level of disorder. The optimal GO loading was found around 0.25 wt. %, which allowed the photocatalyst achieve high photocatalytic performance both in phenol and pesticides photodegradation. Finally, in order to try to elucidate the photocatalytic mechanism of the selected mixture of pesticides three scavengers were employed: methanol to scavenge hydroxyl radicals, formic acid for the photogenerated holes, and copper (II) nitrate to quench the electrons of the conduction band. In conclusion, all these pesticides were mostly photodegraded by the hydroxyl radicals (HO?) produced from the photo-induced holes (h+); given that the oxidant species generated from electrons or mediated by direct mechanism were not relevant.
关键词： Scavengers,TiO2P25-reduced graphene oxide composites,Pesticides,Photo-mechanism
更新于2025-09-23 15:23:52
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Structure variation and luminescence enhancement of BaLaMg(Sb, Nb)O6:Eu3+ double perovskite red phosphors based on composition modulation
摘要： A series of BaLaMgSb1-xNbxO6:Eu3+ double perovskite red phosphors was successfully obtained. X-ray diffraction and Rietveld refinement analyses were conducted to determine the phase information and the detailed structure parameters. The coordinate variations of both La3+/Eu3+ and Sb5+/Nb5+ were discussed to elucidate the influence of B-site ion doping on the lattice variation. Luminescence properties, excitation and emission spectra, were presented to show the advantages of doping with Nb5+ ion. Ultraviolet-vis diffuse reflectance spectra were performed to reveal the reason for the decreased emission intensity under the charge transfer band excitation. Moreover, band gap energy was estimated to clarify the relationship between the increased intensity (λex = 395 and 465 nm) and Nb5+ concentration. Intensity ratios of I(615)/I(590) were performed to show the symmetry variation of the lattice. Thermal quenching property was also investigated and the quenching mechanism was discussed in detail based on the ionization process.
关键词： White LED,Structure variation,Thermal quenching mechanism,Double perovskite
更新于2025-09-23 15:23:52
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Luminescence quenching properties of Sr2Ga2GeO7: Pr3+ with and without traps participation
摘要： Thermal quenching has been extensively regarded as one of the most signi?cant challenges that limits the application of phosphors in today's world. Further e?ort is urgently required to understand the mechanism of thermal stability for achieving the improved performance of these phosphors. Sr2Ga2GeO7: Pr3+ has been synthesized by the conventional high temperature solid state reaction. A dominant green emitting is presented for the partial energy transition quenching process of the 3P0→3H4 emission. The defect states structure is improved via the introducing of co-solvents, and the thermal stability of 1D2→3H4 and 3P0→3H4 levels can be further adjusted. The intervalence charge transfer (IVCT) and traps are introduced to explain the luminescence quenching properties of Sr2Ga2GeO7: Pr3+. The synergy of various models will provide a new idea for improving the luminescence stability of phosphors in the future.
关键词： Partial energy transition,Thermal quenching,IVCT,Mechanism
更新于2025-09-23 15:23:52
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A Novel Actuator-Internal Micro/Nano Positioning Stage with an Arch-Shape Bridge Type Amplifier
摘要： This paper presents a novel actuator-internal two degree-of-freedom (2-DOF) micro/nano positioning stage actuated by piezoelectric (PZT) actuators, which can be used as a fine actuation part in dual-stage system. To compensate the positioning error of coarse stage and achieve a large motion stroke, a symmetrical structure with an arch-shape bridge type amplifier based on single notch circular flexure hinges is proposed and utilized in the positioning stage. Due to the compound bridge arm configuration and compact flexure hinge structure, the amplification mechanism can realize high lateral stiffness and compact structure simultaneously, which is of great importance to protect PZT actuators. The amplification mechanism is integrated into the decoupling mechanism to improve compactness, and to produce decoupled motion in X- and Y- axes. An analytical model is established to explore the static and dynamic characteristics, and the geometric parameters are optimized. The performance of the positioning stage is evaluated through finite element analysis (FEA) and experimental test. The results indicate that the stage can implement 2-DOF decoupled motion with a travel range of 55.4×53.2 μm2, and the motion resolution is 8 nm. The stage can be used in probe tip-based micro/nano scratching.
关键词： Decoupling mechanism,Micro/nano positioning,Actuator-internal configuration,Arch-shape bridge type amplifier
更新于2025-09-23 15:23:52
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Atomic layer deposition of cobalt(II) oxide thin films from Co(BTSA) <sub/>2</sub> (THF) and H <sub/>2</sub> O
摘要： In this work, we have studied the applicability of Co(BTSA)2(THF) [BTSA = bis(trimethylsilyl)amido] (THF = tetrahydrofuran) in atomic layer deposition (ALD) of cobalt oxide thin films. When adducted with THF, the resulting Co(BTSA)2(THF) showed good volatility and could be evaporated at 55 °C, which enabled film deposition in the temperature range of 75–250 °C. Water was used as the coreactant, which led to the formation of Co(II) oxide films. The saturative growth mode characteristic to ALD was confirmed with respect to both precursors at deposition temperatures of 100 and 200 °C. According to grazing incidence x-ray diffraction measurements, the films contain both cubic rock salt and hexagonal wurtzite phases of CoO. X-ray photoelectron spectroscopy measurements confirmed that the primary oxidation state of cobalt in the films is +2. The film composition was analyzed using time-of-flight elastic recoil detection analysis, which revealed the main impurities in the films to be H and Si. The Si impurities originate from the BTSA ligand and increased with increasing deposition temperature, which indicates that Co(BTSA)2(THF) is best suited for low-temperature deposition. To gain insight into the surface chemistry of the deposition process, an in situ reaction mechanism study was conducted using quadrupole mass spectroscopy and quartz crystal microbalance techniques. Based on the in situ experiments, it can be concluded that film growth occurs via a ligand exchange mechanism.
关键词： atomic layer deposition,reaction mechanism,thin films,Co(BTSA)2(THF),cobalt oxide,water
更新于2025-09-23 15:23:52
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KBiO3 as an Effective Visible-Light-Driven Photocatalyst: Stability Improvement by In-situ Constructing KBiO3/BiOX (X = Cl, Br, I) Heterostructure
摘要： Petal-bismuth salt semiconductors are promising as visible-light-driven photocatalysts, but their short service times due to strong oxidation limit their application. In this research, the in-situ construction of a p-n heterojunction, by growing BiOX on a KBiO3 surface, is used as a strategy to improve the performance and stability. Evaluation of the photocatalytic degradation of crystal violet and phenol shows that the KBiO3/BiOX (X = Cl, Br, I) heterostructures exhibit significant improvement in photocatalytic performance and stability compared to KBiO3. The best one, KBiO3/(5.85%)BiOI, shows 98% degradation of crystal violet within 20 min, and of phenol within 1.5 h. No significant performance decay can be detected after repeated use. The development of KBiO3/BiOX heterostructure improves the applicability of KBiO3 as an efficient visible-light-driven photocatalyst.
关键词： Stability,In-situ formation,Heterostructure,Degradation mechanism
更新于2025-09-23 15:23:52
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Degradation of benzothiophene in diesel oil by LaZnAl layered double hydroxide: photocatalytic performance and mechanism
摘要： A new type of photocatalytic La3+–Zn2+–Al3+–MoO4 2- layered double hydroxide (LDH) material (molar ratio, La/Zn/Al = 1:7:2) was prepared by a complexing agent-assisted homogeneous precipitation technique. The structure of the prepared LDH material was systematically studied. Under UV irradiation, the desulfurization efficiency of the LDH material was 87% in 2 h. For La3+–Zn2+–Al3+–MoO4 2- LDH material, the introduction of MoO4 2- increased the interlayer space for promoting the adsorption of benzothiophene (BT), and MoO4 2- might provide active sites for the oxidation of BT, resulting in the high desulfurization efficiency.
关键词： Photocatalytic activities,Catalytic oxidation mechanism,LDH,Homogeneous precipitation
更新于2025-09-23 15:23:52
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Removal of tetracycline by BiOBr microspheres with oxygen vacancies: Combination of adsorption and photocatalysis
摘要： Oxygen vacancy-containing BiOBr microspheres with dual functions of adsorption-photocatalysis were synthesized by a simple solvothermal method. The as-prepared samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance spectroscopy (EPR) and UV–vis diffuse reflectance spectroscopy (DRS). BiOBr microspheres with oxygen vacancies exhibited a higher adsorptive and photocatalytic activity for the removal of tetracycline (TC) than that of defect-deficient BiOBr microspheres. After adsorption for 30 min and visible light irradiation for 90 min, about 94 % of TC was removed by oxygen vacancy-containing BiOBr microspheres, and TC removal efficiency performed effectively in a wide pH range from 3.1 to 11.00. Almost all inorganic anions, such as Cl?, SO2?4, PO3?4, CO2?3 and NO?3, inhibited the removal of TC by BiOBr microspheres and their inhibition effects followed the order of PO3?4 > SO2?4 > CO2?3 > Cl? > NO?3. The surface hydroxyl groups had no effect on TC adsorption, and the adsorption of TC on BiOBr was mainly through the anion exchange process. The existence of oxygen vacancies facilitated the generation of superoxide radicals (O2??), which were the dominant reactive oxygen species for TC degradation in BiOBr suspension. The adsorptive and photocatalytic performance of oxygen vacancy-containing BiOBr decreased to different degrees after three cycles mainly due to the formation of surface complex.
关键词： Mechanism,Photocatalysis,Oxygen vacancy,Adsorption,BiOBr microspheres,Tetracycline
更新于2025-09-23 15:23:52