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- 2019
- Dye-sensitized solar cell
- Photoelectrode
- Light scattering layer
- Transmittance
- White pigment (R902+)
- Rutile titanium dioxide
- Optoelectronic Information Materials and Devices
- Tribhuvan University
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Investigation of strengthening mechanism of commercially pure titanium joints fabricated by autogenously laser beam welding and laser-MIG hybrid welding processes
摘要： In this study, in order to achieve a better understanding of the strengthening mechanism in the commercially pure (CP) Ti welds, autogenously laser beam and laser-MIG hybrid welding of 4.2 mm thick CP-Ti plates were performed and the correlation between microstructure, texture distribution and the mechanical properties were systematically investigated. Microstructural coarsening and increase in microhardness were observed in the HAZ and WZ. The tensile test results suggested the base metal was the weak point of the joint for both welding conditions. The EBSD observations confirmed that a large number of 1012 and 1122 twin grains occurred in the HAZ and WZ of both welded joints, while a higher concentration of these twin grains were found in the laser-MIG hybrid joints. High concentration of the twin grain boundaries can act as barrier to stop dislocation slip during deformation and therefore contribute to the strengthening of the welds. The existence of very small twin grains and acicular α phase in HAZ and WZ would equivalently reduce the averaged grain size and therefore induce an increase in strength based on Hall-Petch’s law. In addition, the averaged Schmid factor of BM is higher than that of the WZ and HAZ in both welding joints suggesting that the grain boundary sliding will take place preferably in BM during deformation so that the necking and fracture occurred in base metal during tensile tests of both welding joint specimens.
关键词： Texture,Mechanical property,Laser-MIG hybrid welding,Strengthening mechanism,Commercially pure titanium,Laser beam welding,Microstructure
更新于2025-11-28 14:24:20
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Effects of titanium on grain boundary strength in molybdenum laser weld bead and formation and strengthening mechanisms of brazing layer
摘要： Molybdenum has tremendous application potential in the nuclear power field, but its application is limited by the grain-boundary embrittlement of fusion-welded joints made of it. In this study, titanium was selected as an alloying element to reduce brittleness of laser weld beads in molybdenum "cladding-end plug" socket joints. Brazing was also performed to enhance the joint strength. Joints with the same strength as base material and a hydraulic bursting pressure of 60 MPa were produced using a combination of the two methods. The analysis indicates the following. After being added to the weld bead, titanium was able to combine with the free oxygen, forming TiO2 and reducing the MoO2 content on grain boundary surface. Oxygen and MoO2 are both the main causes of the embrittlement of molybdenum grain boundaries. In addition, by taking advantage of the high melting point and thermal conductivity of molybdenum, a titanium foil pre-placed between the tube and rod in the socket joint was melted, forming metallurgical bonding, which further improved the bearing capacity of the joint.
关键词： laser beam welding,titanium,brazing,molybdenum,grain boundary embrittlement
更新于2025-11-28 14:24:20
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Influence of Technological Parameters of Direct Laser Deposition Process on the Structure and Properties of Deposited Products from Alloy Ti-6Al-4V
摘要： The technology of direct laser deposition is the most promising for using in various industries. One of the most interesting areas for using this technology is an aviation industry. Due to their unique properties, titanium alloys are widely used in the aircraft industry for gas turbine engine components. In this paper, the effect of DLD process parameters on defect formation and structure is considered. The influence of energy density on the mechanical properties of parts is determined.
关键词： Direct Laser Deposition,additive manufacturing,mechanical properties,Titanium alloys
更新于2025-11-28 14:24:20
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Microstructure and properties of WC reinforced Ni-based composite coatings with Y <sub/>2</sub> O <sub/>3</sub> addition on titanium alloy by laser cladding
摘要： In this study, WC reinforced Ni-based composite coatings with Y2O3 addition were deposited on Ti-6Al-4V titanium substrate by laser cladding. The phases, microstructure, microhardness and wear resistance of the composite coatings were studied by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, microhardness tester and wear tester. The results showed that good metallurgical bonding was achieved between the composite coatings and substrate. The phases mainly were γ -Ni, TiC, TiB2, Ni3B, M23C6 and WC. Most of the WC was dissolved in small pieces of WC during the laser cladding process. The microhardness of the composite coatings was about 3 times that of the titanium substrate and the wear resistance of the composite coatings had a significant increase.
关键词： titanium alloy,microstructure,Laser cladding,Y2O3,WC,Ni-based composite coatings
更新于2025-11-28 14:24:20
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Determination of nanoscale titanium oxide thin film phase composition using X-ray photoelectron spectroscopy valence band analysis
摘要： The phase compositions of nanoscale thick titania films on the titanium were determined using X-ray photoelectron spectroscopy valence band analysis for the first time, by deconvoluting the two-peak structure of valence band into five peaks and analysing the relative peak area. The titania films of thickness varying from about 2 nm to 8 μm were obtained by the air oxidation of commercially pure titanium at different temperatures. The titania films formed on titanium for oxidizing temperatures up to 200 °C were amorphous, with thickness < 10 nm. The sub-stoichiometric oxides present at the TiO2-Ti interface were composed of Ti3+, Ti2+ and Ti1+ states when the film of thickness was < 10 nm. At 300 °C, when the titania film thickness was < 20 nm, it was fully converted to rutile phase and remained stable up to 1000 °C. A broadening of full-width half-maxima of the core level peaks for the titania layers was attributed to the presence of surface hydroxyl group and stress gradient within the oxide layer. The absence of metastable anatase phase in the titania layers at lower temperatures was attributed to the presence of high stresses within the oxide layers owing to their nanoscale thickness.
关键词： X-ray Photoelectron Spectroscopy,Thin film,Valence band,Surface phase composition,Titania,Titanium
更新于2025-11-21 11:24:58
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Laser Alloying of Surface of Ti-5.5Al-2Zr-1Mo-1?V Titanium near-α-Alloy Prepared Via Melted by Pulsed Laser Radiation TiC Particles
摘要： Laser alloying of the surface of Ti-5.5Al-2Zr-1Mo-1 V titanium near-α-alloy was carried out in order to improve the surface properties. The surface of the titanium alloy was being melted by pulsed laser radiation while TiC alloying powder component was being supplied to the laser irradiation zone. As a result of laser alloying, partial melting of the powder particles of titanium carbide and mixing them with the substrate metal resulted in the formation of new disperse TiC phases in the form of dendrites and highly dispersed phases. It is shown that laser alloying of Ti-5.5Al-2Zr-1Mo-1 V titanium near-α-alloy by pulsed laser radiation leads to a 1.4 times increase in hardness of the surface of the titanium alloy and reduces friction coefficient 1.2 times.
关键词： Tribological tests,Laser alloying,Microstructure,Titanium alloy
更新于2025-11-21 11:20:48
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Laser welding characteristics of Ti-Pb dissimilar couples and element diffusion in the molten pool
摘要： Laser welding lead metal to titanium or titanium alloy, which is a typical dissimilar welding process, have a great challenge. Couples of Ti-Pb, Ti6Al4V-Pb were welded by a 3kW continuous wave Nd:YAG laser. The influences of process parameters such as laser power and laser beam offset on welding depth were investigated. Microstructure, element distribution and micro-hardness of the welds were tested. The element diffusion characteristics during laser welding of Ti-Pb couple and Ti6Al4V-Pb couple were studied based on the experiments data. Experimental results show laser beam offset is a primary factor for welding titanium alloy and lead metal, and laser power plays a critical role for welding pure titanium and lead metal. A chemical potential calculation model of Ti-Pb-Al ternary alloy was established. The calculation results show that chemical potential of Ti element increases with enhancing Pb content in Ti-Pb-Al ternary system, however, the chemical potential of Ti element decreases with increasing Pb content in Ti-Pb binary system. According to the calculation results, for Ti-Pb-Al ternary system, because of the Al element in the molten pool, the Ti element tends to diffuse into the Al element, and the diffusion driving force of Ti element to the Pb element is weak. Compared with the Ti-Pb binary system and the Ti-Pb-Al ternary system, it is more likely to form a mixed fusion weld for the binary system, and the mass transfer interface phenomenon is more serious for the ternary system, which is consistent with EDS line scan and microhardness testing results.
关键词： Chemical potential,Interface,Microstructure,Lead metal,Titanium alloy,Laser dissimilar welding
更新于2025-11-21 11:18:25
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A facile dopamine-assisted method for the preparation of antibacterial surfaces based on Ag/TiO2 nanoparticles
摘要： Highly effective antibacterial surfaces are crucial to prevent bacterial infections. In this work, we developed a simple method based on Ag/TiO2 nanoparticles via a dopamine-assisted process with long-term antibacterial efficacy, for the preparation of antibacterial glass surfaces. The chemical and morphological features of the prepared surfaces were investigated through field-emission scanning electron microscopy coupled with energy-dispersive X-ray spectrometry, X-ray diffraction, and X-ray photoelectron spectrometry. The ultraviolet-visible spectroscopy absorption spectra of the prepared glass samples were measured with a spectrophotometer. The prepared Ag/TiO2 nanoparticle modified surfaces exhibited high activity in the elimination of the Gram-negative Escherichia coli and Gram-positive Bacillus subtilis bacteria under visible light and still maintained good antibacterial properties against E. coli after immersion in phosphate buffered saline solution for 60 days.
关键词： Silver,Dopamine,Titanium dioxide,Glass,Antibacterial property
更新于2025-11-21 11:08:12
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Improved photovoltaic performance of perovskite solar cells by utilizing down-conversion NaYF <sub/>4</sub> :Eu <sup>3+</sup> nanophosphors
摘要： Perovskite solar cells assembled with titanium dioxide electron transport layer exhibited brilliant photovoltaic properties due to titanium dioxide having a high electron mobility, appropriate energy level alignment and easy fabrication procedure. However, inherent instability exists in titanium dioxide-based perovskite solar cells because of the ultraviolet photocatalytic activity of titanium dioxide. This results in recombination at the interface of titanium dioxide/perovskite. In this report, the down-conversion nanocrystals film made of europium-doped sodium yttrium fluoride was deposited on the non-conducting side of the conducting glass. The down-conversion nanocrystal layer could absorb high energy ultraviolet photons and converted them to visible light. The layer not only extended the spectral response range for perovskite solar cells but also alleviated the photocatalytic activity of titanium dioxide. The perovskite solar cells with the down-conversion nanocrystals film generated average power conversion efficiency yield of 19.99%, which is much better than that of the device without the down-conversion nanocrystals film (16.99%). The best power conversion efficiency for the device with the down-conversion nanocrystals film was 20.17%. In addition, perovskite solar cells with the down-conversion nanocrystals film showed a small hysteresis.
关键词： titanium dioxide,down-conversion,NaYF4:Eu3+ nanophosphors,photovoltaic performance,perovskite solar cells
更新于2025-11-14 17:04:02
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Carbon Black and Titanium Interlayers Between Zinc Oxide Photo Electrode and Fluorine-Doped Tin Oxide for Dye-Sensitized Solar Cells
摘要： Carbon black and titanium interlayers were deposited on ?uorine-doped tin oxide (FTO) anode layers using radio frequency magnetron sputtering method. On top of them, Zinc oxide (ZnO) photo anode layers were prepared using plasma enhanced chemical vapor deposition technique. ZnO high binding energy as well as good breakdown strength, cohesion, and stability used as a photo electrode material for dye-sensitized solar cells (DSSC), but it does not have a good electrical contact to the FTO anode. To solve this problem, the carbon black and titanium interlayers were deposited. The effect of interlayers on the power conversion ef?ciency (PCE) of DSSCs was investigated. The PCE of the devices with 120-nm-thick interlayers of carbon black or titanium was 5.21 or 4.45%, respectively, which were larger than the PCE of the devices without such interlayers (3.25%). The smooth interface of the carbon black interlayer reduced the interface impedance of the ZnO photo anode effectively. On the other hand, the titanium interlayer with TiO2 on the ZnO side increased the impedance, and decreased the PCE.
关键词： Fluorine-Doped Tin Oxide,Titanium,Carbon Black,Dye-Sensitized Solar Cells
更新于2025-11-14 17:04:02