- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Robust conductive micropatterns on PTFE achieved via selective UV- induced graft copolymerization for flexible electronic applications
摘要： Fabrication of stable and functional patterns on the surface of polytetrafluoroethylene (PTFE) remains a great technical challenge owing to its inertness and high hydrophobicity. Here, we report for the first time the fabrication of functional micro-patterns on the PTFE surface by selectively irradiating plasma-treated PTFE coated with the monomer solution. A series of uniform, highly dense polydopamine methacrylamide (denoted as PDMA) line patterns with the line/pitch width 20μm/20μm and 50μm/50μm were fabricated on the surface of PTFE (denoted as PDMA-p/PTFE) using dopamine methacrylamide (DMA) as the monomer. The surface graft copolymerization occurs attributed to the universal adsorption of DMA and the low grafting energy barrier, comparing with the polymerization energy barrier, which is also demonstrated by the density functional theory (DFT) calculations. Further, robust, well-defined metal Ag or Cu patterns with the strong adhesion strength are fabricated on the surface the PTFE film by electroless deposition, and demonstrated for applications in flexible electronics. The approach is demonstrated to be versatile for fabrication of PDMA micropatterns onto a wide range of polymeric substrates including polypropylene (PP), and acrylonitrile butadiene styrene (ABS).
关键词： dopamine methacrylamide,UV irradiation,graft copolymerization,metal patterns,Surface grafting,PTFE
更新于2025-09-23 15:23:52
-
The role of incidence angle in the morphology evolution of Ge surfaces irradiated by medium-energy Au ions
摘要： Germanium (Ge) surfaces have been irradiated with 26 keV gold (Au) ions at a constant fluence and at incidence angles varying from 0° to 85°. The evolution of the emerging nanostructures is studied by atomic force microscopy (AFM), scanning electron microscopy, x-ray photoelectron spectroscopy (XPS), and cross-sectional transmission electron microscopy. The obtained results are compared with findings reported in the literature. Periodic rippled patterns with the wave vector parallel to the projection of the ion beam direction onto the Ge surface develop between 30° and 45°. From 75° the morphology changes from parallel-mode ripples to parallel-mode terraces, and by further increasing the incidence angle the terraces coarsen and show a progressive break-up of the front facing the ion beam. No perpendicular-mode ripples or terraces have been observed. The analysis of the AFM height profiles and slope distributions shows in the 45°–85° range an angular dependence of the temporal scale for the onset of nonlinear processes. For incidence angles below 45°, the surface develops a sponge-like structure, which persists at higher incidence angles on the top and partially on the face of the facets facing the ion beam. The XPS and the energy-dispersive x-ray spectroscopy evidence the presence of Au nano-aggregates of different sizes for the different incidence angles. This study points out the peculiar behavior of Ge surfaces irradiated with medium-energy Au ions and warns about the differences to be faced when trying to build a universal framework for the description of semiconductor pattern evolution under ion-beam irradiation.
关键词： ion beam irradiation,gold ions,terraces,germanium,binary system,sponge-like structures,ripples
更新于2025-09-23 15:23:52
-
Investigation of gamma irradiation effects on the properties of CdS/p-Si heterostructure
摘要： Cadmium sulfide (CdS) thin films were deposited on p-type Si substrate by thermal evaporation to fabricate the CdS/p-Si heterojunction. Gamma irradiation has been used to modify the microstructural, optical and electrical characteristics of CdS/p-Si heterojunction of various doses in the range (0–80 kGy). X-ray diffraction measurements of the gamma irradiated show the reduction in crystallinity of the CdS thin films. While scanning electron microscope images depicted the average CdS particle size was found to be increased with increasing the gamma irradiation dose. Photoluminescence results revealed that at the specific dose of gamma irradiation was found to create the yellow emission in interstitial sites to the valence band. The I–V characteristics showed the current transport properties effected by the different gamma doses. The values of barrier height, saturation current and ideality factor for the CdS/p-Si heterostructure varied due to the causes like inhomogeneities in the interfacial, defect density, charge distribution on interfacial and interfacial layer thickness after gamma irradiation. The gamma irradiation induced effects and the possible mechanism in CdS/p-Si heterojunction is discussed.
关键词： Heterostructure,Diffuse reflectance,Photoluminescence,Gamma irradiation,Thermal evaporation
更新于2025-09-23 15:23:52
-
Increased resistance of <i>Salmonella</i> Typhimurium and <i>Escherichia coli</i> O157:H7 to 222-nm krypton-chlorine excilamp treatment by acid adaptation
摘要： In this study, we examined the change in resistance of Salmonella Typhimurium and Escherichia coli O157:H7 to 222-nm krypton-chlorine (KrCl) excilamp treatment as influenced by acid adaptation, and identified a mechanism of resistance change. In addition, changes in apple juice quality indicators such as color, total phenols and DPPH free radical scavenging activity during treatment were measured. Acid adapted- and non-acid adapted pathogens were induced by growing the cells in TSB without dextrose (TSB w/o D) at pH 7.3 and TSB w/o D at pH 5.0 adjusted with HCl, respectively. For the KrCl excilamp treatment, acid-adapted pathogens exhibited significantly (P < 0.05) higher D5d values, which indicate dosages required for achieving 5-log reduction, than non-acid adapted pathogens in both commercially clarified apple juice and PBS, and the pathogens in the juice showed significantly (P < 0.05) higher D5d values than those in PBS because of the UV-absorbing characteristics of apple juice. Through mechanism identification, it was found that the generation of lipid peroxidation in cell membrane, inducing cell membrane destruction, of acid adapted cells was significantly (P < 0.05) less than that of non-acid adapted cells for the same amount of reactive oxygen species (ROS) generated at the same dose because the ratio of unsaturated to saturated fatty acids (USFA/SFA) in the cell membrane was significantly (P < 0.05) decreased as a result of acid adaptation. Treated apple juice showed no significant (P > 0.05) differences in quality indicators compared to untreated controls during the treatment of 1773 mJ/cm2.
关键词： acid adaptation,ROS,E. coli O157:H7,apple juice,cell membrane fatty acid,ultraviolet irradiation,S. Typhimurium,222-nm KrCl excilamp
更新于2025-09-23 15:22:29
-
Synthesis and Characterization of ZnO-ZrO <sub/>2</sub> Nanocomposites for Photocatalytic Degradation and Mineralization of Phenol
摘要： ZnO-ZrO2 nanocomposites using zinc (II) acetylacetonate and different ZnO contents (13, 25, 50, and 75% mol) were synthesized through sol-gel method. The synthesis process was strongly related to nanocomposite properties especially on their structural composition. The obtained ZnO-ZrO2 nanomaterials presented tetragonal crystalline structure for zirconia whereas hexagonal one was formed in ZnO. Raman spectroscopy and XRD patterns confirmed the formation of tetragonal zirconia whereas inhibition of monoclinic structure was observed. Addition of ZnO affected the pore size distribution of the composite, and the measured specific surface areas were from 10 m2/g (for pure ZnO) to 46 m2/g (pristine ZrO2). Eg values of ZrO2 were modified by ZnO addition, since calculated values using Kubelka-Munk's function varied from 4.73 to 3.76 eV. The morphology and size of the nanomaterials investigated by electron microscopy showed formation of nanorods for ZnO with sizes ranging from 50 nm to 300 nm while zirconia was formed by smaller particles (less than 50 nm). The main advantage of using the nanocomposite for photocatalytic degradation of phenol was the mineralization degree, since 75ZnO-ZrO2 nanocomposite surpassed mineralization reached by pure ZnO and also inhibited formation of undesirable intermediates.
关键词： sol-gel method,UV-A irradiation,phenol mineralization,photocatalytic degradation,ZnO-ZrO2 nanocomposites
更新于2025-09-23 15:22:29
-
Microwave Hydrothermal Synthesis of In <sub/>2</sub> O <sub/>3</sub> -ZnO Nanocomposites and Their Enhanced Photoelectrochemical Properties
摘要： Indium oxide (In2O3) doped zinc oxide (ZnO) nanocomposites were successfully synthesized through a facile microwave hydrothermal method. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), N2 adsorption–desorption isotherms (BET) and UV-Vis diffuse reflectance spectroscopy. The morphology of In2O3-ZnO composites was observed to be like flowers, and the diameter of particles constituting the porous petal was about 30 nm. The photoelectrocatalytic test results showed that the photoelectrocatalytic methylene blue (MB) degradation efficiency using In2O3-ZnO nanocomposites as photocatalysts under visible light irradiation and a certain voltage could reached above 95.3% after 60 min, much higher than that of In2O3 particles and ZnO particles. The enhanced photoelectrocatalytic activity was attributed to the doping of In2O3 and applied voltage, which beneficially reduced the recombination of electrons and holes in the photoelectrocatalytic process, therefore, it promoted the production of active species (?OH and ?O2-).
关键词： photoelectrochemical properties,visible light irradiation,methylene blue degradation,In2O3-ZnO nanocomposites,microwave hydrothermal synthesis
更新于2025-09-23 15:22:29
-
In-Situ Measurement of Outgassing Generated from EUV Metal Oxide Nanoparticles Resist During Electron Irradiation
摘要： In this study, we prepared the EUV metal resist, which included ZrO2 nano-particle and three type ligands as 2-methyl-2-propenoic acid (MAA), 2-methylpropanoic acid (IBA) and vinylbenzoic acid (VBA). Each resist was prepared by blending each material separately for evaluating the outgassing from EUV resist materials. We prepared three-type samples of ZrO2-MAA, ZrO2-IBA and ZrO2-VBA by coating each resist, and evaluated the outgassing from these samples during irradiation of 2 keV electron by in-situ mass spectrometry. From the results of mass spectrum, we could observe the outgassing of PAG as unique peaks. And each ligand peak was distributed over the low mass range. On the other hand, the ZrO2 peaks could not be observe in mass spectrum of each sample. Thus, we guess that ZrO2 nano-particles might not be evaporating during 2 keV electron irradiation.
关键词： Ligand,EUV metal resist,Electron irradiation,Mass spectrometry,In-situ outgas measurement,ZrO2
更新于2025-09-23 15:22:29
-
Dynamic translocation of stilbene synthase VpSTS29 from a Chinese wild Vitis species upon UV irradiation
摘要： Stilbene phytoalexins derived from grapevine can be rapidly accumulated when exposed to an artificial UV-C treatment. However, the underlying mechanisms involved in this accumulation and translocation are unclear. Here, we describe an investigation of the influence of UV-C treatment on the dynamic subcellular distribution of a member of a stilbene synthase family VpSTS29 derived from Chinese wild Vitis pseudoreticulata W.T. Wang when over-expressed in V. vinifera L. cv. Thompson Seedless. Our results show that VpSTS29-GFP was accumulated at a relatively high level in roots and mature leaves of transgenic grape lines, and was predominantly distributed in the cytoplasm. When exposed to UV-C irradiation, VpSTS29 displayed UV-induced feature coupled with the accumulation of stilbene compounds. Notably, VpSTS29-GFP can be translocated from the cytoplasm into chloroplasts upon UV-irradiation. Leaves from the two VpSTS29-GFP-expressing lines displayed more serious UV damage, showing withering and marginal scorching phenotype, and decreased content of H2O2, compared to the untransformed plant. Also, overexpression of VpSTS29 altered the expression of genes related to redox regulation, stilbene biosynthesis and light stimulus. Co-expression of VpSTS29-GFP with Glycolate oxidase 1 (myc-VpGLO1) confirmed the ability of stilbenes to decrease the content of H2O2 in Arabidopsis mesophyll protoplasts. These results provide new insight into the biological functions and properties of stilbene synthase and its product in response to environmental stimulus.
关键词： Subcellular location,Vitis pseudoreticulata W.T. Wang,UV irradiation,Stilbene synthase,Resveratrol
更新于2025-09-23 15:22:29
-
Some Applications of ANN to Solar Radiation Estimation and Forecasting for Energy Applications
摘要： In solar energy, the knowledge of solar radiation is very important for the integration of energy systems in building or electrical networks. Global horizontal irradiation (GHI) data are rarely measured over the world, thus an artificial neural network (ANN) model was built to calculate this data from more available ones. For the estimation of 5-min GHI, the normalized root mean square error (nRMSE) of the 6-inputs model is 19.35%. As solar collectors are often tilted, a second ANN model was developed to transform GHI into global tilted irradiation (GTI), a difficult task due to the anisotropy of scattering phenomena in the atmosphere. The GTI calculation from GHI was realized with an nRMSE around 8% for the optimal configuration. These two models estimate solar data at time, t, from other data measured at the same time, t. For an optimal management of energy, the development of forecasting tools is crucial because it allows anticipation of the production/consumption balance; thus, ANN models were developed to forecast hourly direct normal (DNI) and GHI irradiations for a time horizon from one hour (h+1) to six hours (h+6). The forecasting of hourly solar irradiation from h+1 to h+6 using ANN was realized with an nRMSE from 22.57% for h+1 to 34.85% for h+6 for GHI and from 38.23% for h+1 to 61.88% for h+6 for DNI.
关键词： solar irradiation,estimation,meteorological data,short time step,forecasting
更新于2025-09-23 15:22:29
-
[IEEE 2018 IEEE 2nd International Conference on Dielectrics (ICD) - Budapest (2018.7.1-2018.7.5)] 2018 IEEE 2nd International Conference on Dielectrics (ICD) - Modelling Charge Generation and Transport in Low Density Polyethylene Irradiated by an Electron-Beam
摘要： One way to bypass charge generation due to injection in an insulator sandwiched between parallel electrodes and submitted to an applied voltage is to implant charges in the material with the help of an electron beam. The electrons position and quantity is theoretically known as long as the beam energy and beam current are known. Low density polyethylene (LDPE) has been characterized with in-situ space charge measurements by pulsed electroacoustic method during irradiation, and with ex-situ measurements while a DC voltage is applied. A fluid charge transport model has been developed using a commercial software, to reproduce the space charge behaviour during and after irradiation. Simulated results during irradiation are first compared to in-situ space charge measurements, in order to validate the model parameters related to e-beam irradiation. Simulations are then performed on post-irradiated samples, polarized under different electric fields. Space charge measurements and current measurements are available for comparison. Simulated results are in relatively good agreement with experimental ones as long as the model parameters are adapted to irradiated low density polyethylene, compared to a best set of parameters adapted uniquely for non-irradiated polyethylene.
关键词： charge generation and transport,fluid model,LDPE,ageing,electron-beam irradiation
更新于2025-09-23 15:22:29