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α-NiS/Bi <sub/>2</sub> O <sub/>3</sub> Nanocomposites for Enhanced Photocatalytic Degradation of Tramadol
摘要： In this study, a series of α-NiS/Bi2O3 composite nanomaterials were prepared and evaluated as efficient photocatalyst for degradation of tramadol under visible light. Two polymorphs of Bi2O3 namely α- (monoclinic) and β- (tetragonal) were prepared by using combustion method and bismuth subcarbonate decomposition route, respectively. A facile method was also developed for synthesis of ultrathin α-NiS nanosheets under mild conditions using hexamethylenetetramine as hydrolyzing agent and Na2S2O3 as sulfur source. The NiS/α-Bi2O3 and NiS/β-Bi2O3 composite materials were thoroughly characterized using a variety of techniques to understand their structural, optical, electrochemical, microstructural and morphological attributes. The α-NiS/Bi2O3 materials exhibited improved visible light absorption, enhanced charge carrier separation and photo-electrochemical properties. The microscopic close contact between the two semiconductor phases is established from the morphological studies. The α-NiS/Bi2O3 materials exhibited excellent photocatalytic activity for aqueous phase degradation of tramadol under visible light irradiation. Particularly, the α-NiS/β-Bi2O3 system is highly active achieving 94% degradation in 3 h. The mechanism of photocatalytic action involves a z-scheme electron transfer from the CB of Bi2O3 to the VB of NiS which is responsible for efficient space separation of charge carriers and their increased reactivity. The ?OH radicals and h+ species have been identified as the major transient species responsible for tramadol oxidation. The photocatalytic method developed in this study can be a viable alternative for TiO2 based UV active photocatalyst studied so far for tramadol degradation.
关键词： Tramadol,Bi2O3,Photocatalysis,α-NiS,Z-scheme
更新于2025-09-23 15:23:52
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Direct Z-scheme MoSe2 decorating TiO2 nanotube arrays photocatalyst for water decontamination
摘要： Exploring a Z-scheme heterojunction photocatalyst with efficient charge separation and outstanding redox ability is necessary but very challenging. Herein, a novel direct Z-scheme MoSe2 decorating TiO2 nanotube arrays photocatalyst (denoted as MoSe2@TNTs) was prepared by a facile in situ hydrothermal method. Few-layer MoSe2 nanosheets distribute on the surface of the TNTs without shielding the tubular structure. Compared with individual TNTs and MoSe2, the as-prepared MoSe2@TNTs composite displays much better photocatalytic activity for eliminating pollutants (such as 4-nitrophenol and hexavalent chromium). Investigation results reveal that TNTs combined with appropriate amount of MoSe2 as co-catalyst has direct Z-scheme construction instead of traditional type-II heterojunction, which can offer abundant photo-generated active species with high redox capacity.
关键词： Photocatalysis,TiO2 nanotube arrays,Z-scheme,Molybdenum diselenide
更新于2025-09-23 15:23:52
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ZnIn2S4 nanosheets decorating WO3 nanorods core-shell hybrids for boosting visible-light photocatalysis hydrogen generation
摘要： We here report the fabrication of a core-shell WO3@ZnIn2S4 heterostructure by an interfacial seeding growth strategy, which is implemented by direct growth of ZnIn2S4 nanosheets on the surface of WO3 nanorods with forming a strong electronic interaction between two semiconductors that are beneficial for promoting the interfacial charge transfer. Systematic studies demonstrate that the WO3@ZnIn2S4 nanohybrids hold superior performance for photocatalytic hydrogen generation under visible light irradiation with a production rate of 3900 mmol g-1 h-1. This work provides an effective approach to construct the direct Z-scheme photocatalytic systems for efficient photocatalytic hydrogen evolution, which would be significant for the design of more direct Z-scheme system for various photocatalytic applications.
关键词： ZnIn2S4 nanosheets,WO3 nanorods,Photocatalytic H2 generation,Visible light,Z-scheme
更新于2025-09-23 15:23:52
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Highly dispersive optical solitons with Kerr law nonlinearity by F-expansion
摘要： This paper employs F-expansion scheme to secure bright, dark, singular and other combo highly dispersive optical solitons when all orders of dispersion up to sixth order are taken into account. There are other solutions that naturally emerge from this scheme as a byproduct. These include Weierstrass function, singular periodic solutions, doubly periodic solutions and so on.
关键词： Complexitons,F-expansion scheme,Solitons
更新于2025-09-23 15:23:52
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Fabrication of high efficiency visible light Z-scheme heterostructure photocatalyst g-C3N4/Fe0(1%)/TiO2 and degradation of rhodamine B and antibiotics
摘要： We have prepared and studied a novel low cost catalyst of g-C3N4/Fe0(1%)/TiO2, using a simple process involving the formation of zero valence iron by chemical reduction. This ternary catalyst g-C3N4/Fe0(1%)/TiO2 was characterized using XRD (X-Ray diffraction), UV–vis spectrum, EDS (Energy Dispersive spectrum) and TEM (transmission electron microscopy), it demonstrated high-visible-light activity in a wide range of pH condition, it can photo-catalytically degraded Rhodamine B (RhB), Tetracycline (TC), and Berberine hydrogen chloride (BH) (～98% in 90 min) under visible light. The high activity arises from the increased harvest of more visible light and the improved separation of photo-excited electrons and holes via Z-scheme and heterojunctions mechanism. Also, the time required to remove 100% RhB, TC, and 96% BH can be shortened from 90 min to 60 min by introducing 3.18 mM Na2SO3 to this photocatalysis system that assisted the generation of reactive oxidizing species and pollutant degradation. The results showed promising application prospect for this developed catalyst and the tested photocatalysis pollutant degradation system.
关键词： Antibiotics,z-scheme heterostructure,Rhodamine B,g-C3N4/Fe0(1%)/TiO2 photocatalyst,Visible-light
更新于2025-09-23 15:23:52
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The superior photocatalytic activity of Nb doped TiO2/g-C3N4 direct Z-scheme system for efficient conversion of CO2 into valuable fuels
摘要： In this study, we firstly aimed to use Nb as dopant to dope into the TiO2 lattice in order to narrow band gap energy or enhance photocatalytic activity of the Nb-TiO2. Then, the prepared Nb-TiO2 was combined with g-C3N4 to establish Nb-TiO2/g-C3N4 direct Z-scheme system for superior reduction of CO2 into valuable fuels even under visible light. The obtained results indicated that the band gap energy of the Nb-TiO2 (2.91 eV) was lower than that of the TiO2 (3.2 eV). In the successfully established Nb-TiO2/g-C3N4 direct Z-scheme system, the photo-excited e- in the CB of the Nb-TiO2 combined with the photo-excited h+ in the VB of the g-C3N4 preserving the existence of e- in the CB of the g-C3N4 and h+ in the VB of Nb-TiO2, and thereby, the system produced numerous amount of available e-/h+ pairs for the reduction of CO2 into various valuable fuels. In addition, the produced e- of the Nb-TiO2/g-C3N4 existing in the CB of the g-C3N4, which the potential energy is approximately - 1.2 V, would be strong enough for the reduction of CO2 to generate not only CH4 and CO but also HCOOH. Among established Nb-TiO2/g-C3N4 materials, the 50Nb-TiO2/50g-C3N4 material was the best material for the CO2 reduction.
关键词： Nb dopant,CO2 reduction,Nb-TiO2,g-C3N4,direct Z-scheme
更新于2025-09-23 15:23:52
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Facile assembly of g-C3N4/Ag2CO3/graphene oxide with a novel dual Z-scheme system for enhanced photocatalytic pollutant degradation
摘要： In this study, ternary catalyst g-C3N4/Ag2CO3/graphene oxide was synthesized through a simple chemical precipitation method at room temperature. The CN/AC/GO composite was employed to degrade antibiotics under visible light irradiation. And the results indicated that the composite possessed excellent photocatalytic performance, which could remove 81.6% tetracycline (TC) after 60 min of irradiation. The PL, EIS, PC and UV–vis DRS tests demonstrated that enhanced photocatalytic e?ciency could be attributed to rapid charge transfer, low recombination rate of photo-induced electron-hole pairs, as well as superior light absorption capability. Moreover, three-dimensional excitation-emission matrix ?uorescence spectra (3D EEMs) were employed to further grasp the behaviors of TC molecules in the process of degradation reaction. In addition, the liquid chromatography-mass spectrometry (LC-MS) was carried out to explore the intermediates during the photocatalytic reaction. Meanwhile, the in?uences of initial TC concentration, light source, supporting electrolytes and water sources were explored from the perspective of practical application. Furthermore, the appearance of a small amount of Ag nanoparticles (NPs) not only accelerated the charge transfer, but also improved the stability of catalyst. The composite also possessed high stability and reusability, which were essential in practical application.
关键词： g-C3N4,Double Z-scheme mechanism,Sewage treatment,Photocatalysis
更新于2025-09-23 15:23:52
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[IEEE 2018 Eleventh International Conference "Management of large-scale system development" (MLSD 2018) - Moscow (2018.10.1-2018.10.3)] 2018 Eleventh International Conference "Management of large-scale system development" (MLSD - Optimization of the Structure and Parameters of the Light Cycle Aimed at Improving Traffic Safety at an Intersection
摘要： Formulas for evaluating structural safety for an arbitrary scheme of the road network segment are proposed. On their basis the problem of structural optimization of the traffic light cycle aimed at improving traffic safety is set. The similar optimization problem with respect to traffic intensity is set as well. Approaches to their solution are offered.
关键词： scheme of phase separation,microscopic models of traffic flows,optimization,safety of the road network segment,controlled intersection,computational experiments
更新于2025-09-23 15:22:29
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The Temperature Dependences of the Electron-Piezoelectric Potential Phonon Interacting System of Quasi Two Dimensional System in GaN and ZnS
摘要： We investigated theoretically the temperature dependence of the quantum optical transition of quasi 2-Dimensional Landau splitting system, in GaN and ZnS. We apply the Quantum Transport theory (QTR) to the system in the con?nement of electrons by square well con?nement potential. We use the projected Liouville equation method with Equilibrium Average Projection Scheme (EAPS). Through the analysis of this work, we found the increasing properties of Quantum Transition Line Shapes (QTLSs) and the Quantum Transition Line Widths (QTLWs) of CdS and GaN with the temperature we also found that QTLW, (cid:2)(cid:3)T (cid:4) of ZnS < (cid:2)(cid:3)T (cid:4) of GaN in (cid:5) = 394 (cid:6)m.
关键词： Quantum Transport Theory,Quantum Transition Line Widths (QTLW),Quantum Transition Line Shapes (QTLS),GaN and ZnS,Cyclotron Resonance,Equilibrium Average Projection Scheme (EAPS),Electron Phonon Coupling System
更新于2025-09-23 15:22:29
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Evaluating impact damage to fabric-based personal armor by infrared NDT
摘要： The paper considers the thermo-mechanical mechanism of interaction between the damage agents and armor protection made of polymer fabrics. A simplified mathematical model is proposed to describe the deceleration of a damage agent within an armor fabric due to the dissipation of energy expended on irreversible stretching deformations of fabric fibers, as well as fiber slipping friction and material heating. Woven fabric layers are replaced by solid layers characterized by averaged stiffness and viscosity. A discrete numerical model of a solid material is proposed to reduce a problem with a finite number of degrees of freedom; motion equations are obtained on the basis of the Lagrange equations of the second kind, and for their integration, a stable non-conservative difference scheme is used. The software implementation is based on a functional-object paradigm which allows the modeling of conjugated processes. The parameters of governing equations are identified by using the experimental data. Some illustrative examples of interaction between damage agents and armor barriers with different arrangement of fibers are presented. The proposed model can be used to predict the quality of armor protection with the changing number and location of fibers, as well as to test the armor protection by applying the technique of infrared thermography.
关键词： Armor protection,mathematical model,irreversible deformation,infrared thermography,energy absorption,numerical scheme,composite material,fiber friction
更新于2025-09-23 15:22:29