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- 实验方案
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Damp-Heat-Stable, High-Efficiency, Industrial-Size Silicon Heterojunction Solar Cells
摘要： Silicon heterojunction (SHJ) solar cells hold the power conversion efficiency (PCE) record among crystalline solar cells. However, amorphous silicon is a typical high-entropy metastable material. Damp-heat aging experiments unveil that the amorphous/crystalline silicon interface is susceptible to moisture, which is potentially the biggest stumbling block for mass production. By capping SiNx and SiOx dielectrics, the absolute PCE degradation is predicted to be only (cid:1)0.6% after a 30-year installation. This demonstrates the SHJ solar cell is a highly promising candidate for next-generation photovoltaics.
关键词： High efficiency,Amorphous silicon,Mass production,Damp-heat stability,Silicon heterojunction solar cells
更新于2025-09-23 15:21:01
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Surface Modifications for Light Trapping in Silicon Heterojunction Solar Cells: A Brief Review
摘要： Reducing crystalline silicon (c-Si) wafer thickness is an effective method to reduce the fabrication cost as it constitutes a major portion of the photovoltaic module cost. However, the open-circuit voltage and fill factor depend on the wafer thickness; further, the short-circuit current density (JSC), affects the device performance negatively. Therefore, light trapping is vital for increasing the JSC of Si solar cells. Consequently, it is essential for improving the conversion efficiency of the solar cell and reduce its production cost by decreasing the wafer thickness. It can be assumed that the thickness of the Si wafer will gradually achieve a minimum value of ~ 100?μm in the future. Therefore, reducing the as-cut wafer thickness will result in a more efficient use of Si. This paper reports the surface modification for light trapping based on the Si solar cell application. Additionally, we introduce methods for surface modification, such as front-side texturing and rear-side polishing.
关键词： Texturing,Polishing,Si solar cell,Surface modification,Light trapping,High efficiency
更新于2025-09-23 15:21:01
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Synergetic interface and morphology modification to achieve highly efficient solution-processed sky-blue organic light-emitting diodes
摘要： Solution-processed organic light-emitting diodes (OLEDs), especially blue OLEDs, generally suffer from the low efficiency. Herein, we report an efficient approach to achieve high efficiency by synergetic interface and morphology modification with a polymer, Poly(9-vinylcarbazole) (PVK). Sky-blue thermally activated delayed fluorescent (TADF) material, 10-(4-(4,6-diphenyl-1,3,5- triazin-2-yl)phenyl)-10H- spiro[acridine-9,9-fluorene] (SpiroAC-TRZ), is used as the emitter. The incorporation of PVK thin layer at the hole injection layer/emission layer (EML) interface and a small amount of PVK inner the EML modify the carrier behaviors at the interface and improve the EML morphology. As a result, balanced carrier distribution and reduced carrier recombination are realized at the interface and inner the EML. Through these strategies, the maximum external quantum efficiency and current efficiency of the optimal OLED achieve 25.1% and 53.5 cd/A. To the best of our knowledge, the efficiencies are the highest values ever achieved by the solution-processed sky-blue TADF OLEDs.
关键词： Blue organic light-emitting diodes,Thermally activated delayed fluorescence,High efficiency,All-solution process,Film morphology
更新于2025-09-23 15:21:01
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Understanding partial shading effects in shingled PV modules
摘要： Shingled solar modules are one of several technologies currently being considered to obtain higher solar module efficiencies. Using equivalent circuit modelling this paper investigates the robustness of shingled modules to partial shading with respect to the power produced and the power dissipated in shaded shingles. The modeling results are experimentally verified. We find that power losses in shingled modules can be larger than in conventional modules for similar shading conditions. The risk of significant local heating resulting from partial shading, potentially leading to catastrophic module failure can also be higher in shingled modules due to the substantially higher reverse biases experienced by shaded shingles. Both risks can effectively be mitigated by operating each shingled module at its own maximum power point, for instance by using module level power electronics on each module or by incorporating a sufficient number of bypass diodes into the module design.
关键词： Partial shading,High efficiency modules,Hot spots,Modelling,Shingled modules
更新于2025-09-23 15:21:01
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One Octave Bandwidth Rectifier With a Frequency Selective Diode Array
摘要： In this paper, a high-efficiency rectifier with one octave bandwidth is proposed by proposing a diode array with a frequency selective topology. With the frequency selective topology, the low-and high-band rectifiers are combined together without extra matching circuit at the input leading to a high-efficiency broadband design. For validation, a prototype rectifier was fabricated and characterized. The measured results show that the RF-dc power conversion efficiency (PCE) maintains above 70% from 1.75 to 3.55 GHz at an input power of 10 dBm. The measured PCE remains more than 50% within 1.4–3.7 GHz and the |S11| is lower than ?10 dB from 1.7 to 3.6 GHz.
关键词： energy harvesting (EH),frequency selection,high efficiency,Broadband RF rectifier,impedance matching,wireless power transfer (WPT)
更新于2025-09-23 15:21:01
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Spontaneously Selfa??Assembly of a 2D/3D Heterostructure Enhances the Efficiency and Stability in Printed Perovskite Solar Cells
摘要： As perovskite solar cells (PSCs) are highly efficient, demonstration of high-performance printed devices becomes important. 2D/3D heterostructures have recently emerged as an attractive way to relieving the film inhomogeneity and instability in perovskite devices. In this work, a 2D/3D ensemble with 2D perovskites self-assembled atop 3D methylammonium lead triiodide (MAPbI3) via a one-step printing process is shown. A clean and flat interface is observed in the 2D/3D bilayer heterostructure for the first time. The 2D perovskite capping layer significantly suppresses nonradiative charge recombination, resulting in a marked increase in open-circuit voltage (VOC) of the devices by up to 100 mV. An ultrahigh VOC of 1.20 V is achieved for MAPbI3 PSCs, corresponding to 91% of the Shockley–Queisser limit. Moreover, notable enhancement in light, thermal, and moisture stability is obtained as a result of the protective barrier of the 2D perovskites. These results suggest a viable approach for scalable fabrication of highly efficient perovskite solar cells with enhanced environmental stability.
关键词： stability,2D/3D heterojunctions,self-assembly,perovskite solar cells,high efficiency
更新于2025-09-23 15:19:57
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Effect of Solvent Additives on the Morphology and Device Performance of Printed Non-fullerene Acceptor Based Organic Solar Cells
摘要： Printing of active layers of high-efficiency organic solar cells and morphology control by processing with varying solvent additive concentrations are important to realize real-world use of bulk-heterojunction photovoltaics as it enables both, up-scaling and optimization of the device performance. In this work, active layers of the conjugated polymer with benzodithiophene units PBDB-T-SF and the non-fullerene small molecule acceptor IT-4F are printed using meniscus guided slot-die coating. 1,8-diiodoctane (DIO) is added to optimize the power conversion efficiency (PCE). The effect on the inner nano-structure and surface morphology of the material is studied for different solvent additive concentrations with grazing incidence small angle X-ray scattering (GISAXS), grazing incidence wide angle X-ray scattering (GIWAXS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). Optical properties are studied with photoluminescence (PL), UV/Vis absorption spectroscopy and external quantum efficiency (EQE) measurements and correlated to the corresponding PCEs. The addition of 0.25 vol% DIO enhances the average PCE from 3.5 to 7.9 % whereas at higher concentrations the positive effect is less pronounced. A solar cell performance of 8.95 % is obtained for the best printed device processed with an optimum solvent additive concentration. Thus, with the large-scale preparation method printing similarly well working solar cells can be realized as with the spin-coating method.
关键词： slot-die coating,solvent additives,small molecule acceptor,high-efficiency organic solar cells,printed organic solar cells
更新于2025-09-23 15:19:57
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Large organic cation incorporation induces vertical orientation growth of Sn-based perovskites for high efficiency solar cells
摘要： The potential toxic issue of lead content is still a problem for prohibiting the commercialization of lead halide perovskite solar cells (PSCs). as an element of group 14 metals, tin (Sn) is the most likely substitute for lead element in perovskites. However, Sn-based PSCs still suffer from the low power conversion efficiency (PCE) because Sn2+ in tin-based perovskites is easily oxidized into Sn4+ once exposed to air. To fabricate stable and efficient Sn-based PSCs, herein we incorporate large ethylammonium (EA+) cation into CH3NH3SnI3 (MASnI3) abided by the Goldschmidt tolerance factor to fabricate vertically oriented 2D/3D mixed perovskite films. The vertically oriented structure provides a direct pathway for electron and hole transport. As a result, the PCE is highly improved to 9.24% and the corresponding PSC still retains 95% of the initial efficiency after being kept for 30 days without encapsulation in the glovebox. Therefore, our results suggest a promising strategy to develop highly efficient and stable Sn-based PSCs.
关键词： high efficiency solar cells,Sn-based perovskites,vertical orientation growth,stability,ethylammonium incorporation
更新于2025-09-23 15:19:57
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MACl Induced Intermediate Engineering for High-performance Mixed Cation Perovskite Solar Cells
摘要： Recently, mixed-cation perovskite has been extensively used for high-performance solar cells. Nevertheless, the mixed-cation perovskite based on formamidinium methylammonium lead tri-iodide (FAxMA1-xPbI3) fabricated through the existing methods often suffers phase stability and much trap density. Herein, we demonstrate a facile intermediate engineering approach to improve the quality of mixed-cation perovskite based on FAxMA1-xPbI3. Varying concentrations of methylammonium chloride (MACl) is used to treat FA-MA-PbI3-solvent intermediate. It is noted that MACl has a strong impact on the crystallization kinetics, charge carrier dynamics as well as defect density of obtained perovskite. The mixed-cation perovskite treated with 20 mg mL-1 MACl yields large grain size, highly uniform morphology, better crystalline stability. Subsequently, the device with acquired high-quality mixed-cation perovskite shows a high efficiency of 20.40%, which is obviously higher than that obtained from the traditional non-treated method. Moreover, the device prepared through the developed method could retain over 85% of the initial efficiency after 860 h at room temperature.
关键词： stability,MACl-treatment,intermediate engineering,mixed-cation perovskite,high efficiency
更新于2025-09-23 15:19:57
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Closed Loop Control of a Series Class-E Voltage-Clamped Resonant Converter for LED Supply with Dimming Capability
摘要： In this work, a new closed-loop control system is applied to a class-E resonant DC–DC converter with voltage clamp used for light-emitting diode (LED) supply. The proposed power topology was first described by Ribas et al. in a recent work. In the present paper, the LED current is sensed and used to implement a feedback control loop instead of the simplified feedforward scheme used in this previous reference. To design the control, a novel, simplified small-signal model is presented. This model is used to analyze the converter behavior as a function of the output power. The proposed approximation is significantly simpler than the multifrequency averaging technique normally used to analyze resonant converters. The feedback control loop is designed to reduce the LED low frequency current ripple while providing dimming control. Both the model and the control are verified by simulation and laboratory experimentation and the results obtained are in good accordance with the expected values.
关键词： small-signal dynamic model,light-emitting diode (LED) driver,high efficiency LEDs,resonant DC–DC converter,Class-E inverter,single-switch topology,closed-loop control,voltage clamp
更新于2025-09-23 15:19:57