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Oxygen doped MoS <sub/>2</sub> quantum dots for efficient electrocatalytic hydrogen generation
摘要： In this study, we report an oxygen-doped MoS2 quantum dot (O–MoS2 QD) hybrid electrocatalyst for the hydrogen evolution reaction (HER). The O–MoS2 QDs were prepared with a one-pot microwave method by hydrazine-mediated oxygen-doping. The synthetic method is straightforward, time-saving, and can be applied in large scale preparation. Ultra-small O–MoS2 QDs with the average size of 5.83 nm and 1–4 layers can be uniformly distributed on the surface of reduced graphene oxide (RGO). Benefited from the unique structure and the doping effect of oxygen in the MoS2 QDs and the great number of active sites, the O–MoS2 QD hybrid displayed outstanding electrocatalytic performance toward HER. A low overpotential of 76 mV at 10 mA/cm2 and a Tafel slope of 58 mV/dec were obtained in an acidic solution toward HER. Additionally, the resultant O–MoS2 QD hybrid also exhibited excellent stability and durability toward HER, displaying negligible current density loss after 1000 cycles of cyclic voltammetry. The design and synthesis of the electrocatalyst in this work open up a prospective route to prepare active and stable electrocatalysts toward substituting precious metals for hydrogen generation.
关键词： electrocatalytic hydrogen generation,oxygen-doped MoS2 quantum dots,microwave synthesis,reduced graphene oxide,hydrogen evolution reaction
更新于2025-09-19 17:13:59
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Laser Programmable Patterning of RGO/GO Janus Paper for Multiresponsive Actuators
摘要： Graphene oxide (GO) with tunable physical/chemical properties is a versatile material for smart bimorph actuators. Using GO or its derivatives (e.g., reduced GO, RGO) as an active material, actuators can be manipulated under various external stimuli including moisture, light, temperature, and electricity. However, most of these GO-based actuators respond to a solo stimulus, which limits its cutting-edge applications in soft robotics. Here, the programmable patterning of RGO/GO Janus paper using a threshold-controlled direct laser writing (DLW) technology is reported. By combining the RGO/GO Janus paper with a common thermally expansive polymer layer, a moisture, light, and electricity multiresponsive actuator is fabricated, in which the RGO interlayer plays multiroles including moisture-passive layer, photothermal/electrothermal layer, thermal conductive layer, and inert layer for thermal expansion. As a proof of concept, multiresponsive actuators including a bidirectional cantilever and a smart curtain are fabricated, demonstrating the great potential for developing soft robots.
关键词： soft robots,laser reduction,multiresponsive actuators,reduced graphene oxide
更新于2025-09-19 17:13:59
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Enhancing effects of reduced graphene oxide on photoluminescence of CsPbBr <sub/>3</sub> perovskite quantum dots
摘要： The composites of CsPbBr3 perovskite quantum dots (PeQDs) and reduced graphene oxide (RGO) nanosheets have been synthesized by an in-situ solution reaction. The amount of RGO can significantly affect the photoluminescence of PeQDs. Varying with the amount of RGO, the photoluminescence quantum yield can be tuned from 48.4% to 69.3%. PL decay analysis indicates that the radiative decay rate and charge transfer become faster with increasing the amount of RGO. The ellipsomitric data can be described by a double Lorentz oscillator model. The comparison between bare and composite samples indicates that the complex refractive index can be affected by RGO composite. Numerical simulations on the electric field distribution for PeQD/RGO show that the local electric field around CsPbBr3 QDs is increased by surface plasmon resonance on the surface of RGO nanosheet. These results suggest that PeQD/RGO composite can be used for highly efficient light emitting devices.
关键词： FDTD,Surface plasmon resonance,Photoluminescence,Reduced graphene oxide,CsPbBr3 quantum dots
更新于2025-09-19 17:13:59
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Covalently bonded polyaniline-reduced graphene oxide/single-walled carbon nanotubes nanocomposites: influence of various dimensional carbon nanostructures on the electrochromic behavior of PANI
摘要： In this paper, water-dispersible and covalently bonded polyaniline-carbon nanostructures, including polyaniline-reduced graphene oxide (PANI-rGO), polyaniline-single-walled carbon nanotubes (PANI-SWCNTs), and polyaniline-reduced graphene oxide/single-walled carbon nanotube (PANI-rGO/SWCNTs) nanocomposites, were synthesized by grafting PANI onto p-phenylenediamine (PPD)-functionalized graphene oxide (GO) or single-walled carbon nanotubes (SWCNTs) using polystyrene sulfonate (PSS) as a macromolecular dopant agent. The structures and morphologies of the PANI, PANI-rGO, PANI-SWCNTs, and PANI-rGO/SWCNTs nanocomposites were characterized by Fourier transform infrared spectroscopy and scanning electron microscopy. The cyclic voltammetry and UV–vis spectra were performed on an electrochemical workstation and a UV–vis spectrometer, respectively. The results show that the electrochromic and electrochemical properties of nanocomposites can bene?t from the high conductivity of SWCNTs and the abundant active sites of rGO. When SWCNTs and rGO work together, their respective shortcomings are overcome, allowing the nanocomposite to exhibit the best electrochemical and electrochromic properties. The optical contrast increased from 0.38 for PANI to 0.52 for PANI-rGO/SWCNTs. The coloring and bleaching times decreased from 2.59 s and 2.39 s, respectively, for PANI to 1.33 and 0.78 s, respectively, for PANI-rGO/SWCNTs. The charge transfer resistance (Rct) decreased from 135 Ω for PANI to 30 Ω for PANI-rGO/SWCNTs. The synergistic effect of PANI, rGO, and SWCNTs can signi?cantly improve the electrochromic ability of PANI.
关键词： single-walled carbon nanotubes,reduced graphene oxide,electrochromic,polyaniline,nanocomposites
更新于2025-09-19 17:13:59
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Microwave assisted synthesis of CuInGaSe2 quantum dots and spray deposition of their composites with graphene oxide derivatives
摘要： In this contribution, we explore a spray deposition technique to prepare thin films based on nanocomposites of graphene oxide (GO) or reduced graphene oxide (rGO) with CuInGaSe2 quantum dots (QD) synthesized by a microwave-assisted method. Small nanocrystals in the tetragonal phase and emitting light at 650 nm were obtained. Water-based solutions of the nanocomposites were sprayed onto transparent conductive glass substrates using an automated ultrasonic spray system and the resulting thin films were evaluated with respect to their morphological and electrochemical properties. The distribution and organization of the graphene sheets in the composites were affected by the interaction between the nanocrystals and GO or rGO, which also interfered on the electronic properties. In addition, we demonstrated a possible application of the thin film based on the rGO-QD composite as a counter electrode in dye-sensitized solar cells.
关键词： copper indium gallium selenide,dye-sensitized solar cell,graphene oxide,microwave assisted synthesis,spray deposition,reduced graphene oxide
更新于2025-09-16 10:30:52
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[IEEE 2019 18th International Conference on Optical Communications and Networks (ICOCN) - Huangshan, China (2019.8.5-2019.8.8)] 2019 18th International Conference on Optical Communications and Networks (ICOCN) - Composite transparent conductive electrode for printed electronic devices
摘要： The new transparent conductive electrode consists of three materials: silver nanowires (AgNWs), zinc oxide nanoparticles (ZnO), and reduced graphene oxide (rGO). We prepared a silver nanowire electrode by spin coating a silver nanowire solution on a glass substrate，the zinc oxide nanoparticles covered the silver nanowire grid and filled the gap of silver nanowire, which enhanced the adhesion of silver nanowire to the substrate. The outermost reduced graphene oxide provides protection for the material and improves the stability of the electrode in an air environment. The AgNWs/ZnO/rGO composite electrode prepared has a sheet resistance of about 9.96 ?/sq and a light transmittance of 71% (T550), which has good photoelectric properties. Experimental results show that the composite electrode has long-term stability in air.
关键词： composite electrode,silver nanowire,reduced graphene oxide,zinc oxide
更新于2025-09-16 10:30:52
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Solution preparation of molybdenum oxide on graphene: a hole transport layer for efficient perovskite solar cells with a 1.12??V high open-circuit voltage
摘要： Recently, based on the tremendous progresses in performance of perovskite solar cells (PSCs), the inverted planar PSCs have attracted attentions for future applications. Since the traditional poly(3,4-ethylenedioxythiophene) hole transport layer could cause a loss of open-circuit voltage (Voc), some organic and inorganic alternatives have been widely investigated. However, the Voc is still below for the demand of optimized value. Here, we demonstrate that the reduced graphene oxide (RGO) doping is a facile and effective method to make molybdenum oxide (MoOx) as a promising hole transport layer (HTL) for high-performance PSCs. The conductive MoOx:RGO HTL can facilitate perovskite crystallization and reduce the potential losses of Voc in devices. Thus, a high PCE of up to 18.15% is achieved which simultaneously possesses a high Voc of 1.12 V. With this strategy, the MoOx:RGO provides a novel hole transport layer for high performance and decently stable optoelectronic devices. More importantly, it opens up the research significance of doping in inorganic buffer interlayers for the perovskite solar cells.
关键词： open-circuit voltage,reduced graphene oxide,molybdenum oxide,hole transport layer,perovskite solar cells
更新于2025-09-16 10:30:52
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Synthesis and Characterization of Laser Induced Graphene (LIG) and laser Reduced Graphene Oxide (lrGO) by using a pulsed CO <sub/>2</sub> laser
摘要： We detail a method to produce graphite materials with a three-dimensional, flexible and porous structure obtained from the exposure to CO2 laser radiation. One of them is Laser Induced Graphene (LIG) grown from an insulating polyimide as raw material, and the other is laser reduced graphene oxide (lrGO), obtained from a graphene oxide (GO) thin film. For both materials, we describe their morphology, crystalline structure and electrical characterizations. These materials have important applications in organic electronics technology.
关键词： LIG,laser reduced graphene oxide,Laser Induced Graphene,lrGO,flexible electronics,CO2 laser
更新于2025-09-16 10:30:52
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The Study on Tuning Photoluminescence of Colloidal Graphene Quantum Dots Synthesized through Laser Ablation
摘要： We report photoluminescence study of Colloidal Graphene Quantum Dots (GQDs) that synthesized from ablation of rGO solution. The rGO solution was ablated using 800 nm Ti-Sapphire femtosecond laser by varying the synthesize parameters such as laser power and ablation time. We observed that changing laser power 1 Watt to become 1.7 Watt and time ablation 20 minutes to become 60 minutes will alterate the Photoluminescence (PL) curve peak of GQDs. In case of ablation power variation, PL data shows that the PL curve peak excited by 280 nm laser changed from 369.09 nm to 371.02 nm, and when it excited by 290 nm the PL curve peak slightly changed from 388.17 nm to 393.8 nm. The alteration of Photoluminescence peak is also observed in the variation of time ablation experiment, The PL curve peaks from GQDs time ablation variation samples excited by 280 nm were slightly changed from 376.81 nm to 373.59 nm, and when it excited by 290 nm laser, the PL curve peak is 391.55 nm then changed to 392.11. The change of PL peak on laser power or time ablation variation shows that both parameters will alter either the size, shape, or the edge-type of GQDs.
关键词： Laser Ablation,Ti-Sapphire Femtosecond Laser,Graphene Quantum Dots,Photoluminescence,Reduced Graphene Oxide
更新于2025-09-16 10:30:52
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Electrochemical Fabrication of rGO-embedded Ag-TiO2 Nanoring/Nanotube Arrays for Plasmonic Solar Water Splitting
摘要： Effective utilization of hot electrons generated from the decay of surface plasmon resonance in metal nanoparticles is conductive to improve solar water splitting efficiency. Herein, Ag nanoparticles and reduced graphene oxide (rGO) co-decorated hierarchical TiO2 nanoring/nanotube arrays (TiO2 R/T) were facilely fabricated by using two-step electrochemical anodization, electrodeposition, and photoreduction methods. Comparative studies were conducted to elucidate the effects of rGO and Ag on the morphology, photoresponse, charge transfer, and photoelectric properties of TiO2. Firstly, scanning electron microscope images confirm that the Ag nanoparticles adhered on TiO2 R/T and TiO2 R/T-rGO have similar diameter of 20 nm except for TiO2 R-rGO/T. Then, the UV–Vis DRS and scatter spectra reveal that the optical property of the Ag-TiO2 R/T-rGO ternary composite is enhanced, ascribing to the visible light absorption of plasmonic Ag nanoparticles and the weakening effect of rGO on light scattering. Meanwhile, intensity-modulated photocurrent spectroscopy and photoluminescence spectra demonstrate that rGO can promote the hot electrons transfer from Ag nanoparticles to Ti substrate, reducing the photogenerated electron–hole recombination. Finally, Ag-TiO2 R/T-rGO photoanode exhibits high photocurrent density (0.98 mA cm?2) and photovoltage (0.90 V), and the stable H2 evolution rate of 413 μL h?1 cm?2 within 1.5 h under AM 1.5 which exceeds by 1.30 times than that of pristine TiO2 R/T. In line with the above results, this work provides a reliable route synergizing rGO with plasmonic metal nanoparticles for photocatalysis, in which, rGO presents a broad absorption spectrum and effective photogenerated electrons transfer.
关键词： TiO2 nanoring/nanotube hierarchical structure,Spectral responses,Plasmonic Ag nanoparticles,Reduced graphene oxide,Water splitting
更新于2025-09-16 10:30:52