研究目的
Investigating the defect physics behind Light and elevated Temperature-Induced Degradation (LeTID) of multicrystalline silicon solar cells, focusing on the roles of hydrogen and metallic impurities.
研究成果
The study concludes that hydrogen and a metallic impurity are involved in the LeTID defect physics in mc-Si solar cells. Tuning SiNx:H layer properties to minimize hydrogen in-diffusion and thinning mc-Si wafers are effective strategies to mitigate LeTID.
研究不足
The study's methodology relies on indirect measurements of hydrogen content and defect concentrations, which may introduce uncertainties. Additionally, the specific metallic impurity involved in LeTID is not conclusively identified.
1:Experimental Design and Method Selection:
The study involves varying the composition of SiNx:H layers deposited on silicon wafers to adjust hydrogen content introduced during firing. Lifetime measurements are performed under illumination at elevated temperatures to observe degradation and regeneration effects.
2:Sample Selection and Data Sources:
High-purity float-zone silicon (Fz-Si) and multicrystalline silicon (mc-Si) wafers are used. Hydrogen content is measured on Fz-Si wafers, while LeTID effects are observed on mc-Si wafers.
3:List of Experimental Equipment and Materials:
Includes plasma-enhanced chemical vapor deposition (PECVD) for SiNx:H layer deposition, industrial conveyor-belt furnace for firing, and photoconductance-based lifetime measurements (WCT120TS, Sinton Instruments).
4:Experimental Procedures and Operational Workflow:
Wafers are cleaned, coated with SiNx:H layers, fired, and then subjected to lifetime measurements under controlled illumination and temperature conditions.
5:Data Analysis Methods:
The study uses injection-dependent lifetime measurements and Shockley–Read–Hall equation analysis to determine defect concentrations and electron-to-hole capture ratios.
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