研究目的
To develop a self-adaptive model for the prediction of soil organic matter using mid-infrared photoacoustic spectroscopy to improve the accuracy and applicability of SOM determination.
研究成果
The self-adaptive model based on FTIR-PAS spectra significantly improved the accuracy and applicability of SOM prediction in paddy soils compared to the conventional PLS model. This approach provides a robust tool for rapid and cost-effective soil quality assessment.
研究不足
The study's limitations include the specific focus on paddy soils from Lishui, China, which may limit the model's applicability to other soil types and regions. Additionally, the model's performance is dependent on the quality and representativeness of the spectral database.
1:Experimental Design and Method Selection:
The study utilized FTIR-PAS spectra for SOM prediction, employing a self-adaptive PLS model based on Euclidean distance for sample identification and optimal parameter selection.
2:Sample Selection and Data Sources:
933 paddy soil samples were collected from Lishui, China, air-dried, sieved, and analyzed for SOM content using the hydrated heat K2Cr2O7 oxidation-colorimetry method.
3:List of Experimental Equipment and Materials:
Nicolet 6700 spectrophotometer equipped with a photoacoustic cell (Model 300, MTEC), MATLAB R2013a software for data analysis.
4:Experimental Procedures and Operational Workflow:
Soil samples were scanned from 4000 to 400 cm?1, spectra were preprocessed with a Savitzky–Golay smoothing filter, and the self-adaptive model was applied for SOM prediction.
5:Data Analysis Methods:
The predictive capabilities of the self-adaptive and conventional PLS models were compared using R2, RMSEP, and RPD values.
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