研究目的
Investigating the residual stresses and fracture mechanisms in crystalline silicon solar cells within photovoltaic modules to understand and mitigate performance degradation and warranty issues.
研究成果
The study quantitatively characterized residual stresses in generic design sc-Si cells for the first time, revealing high residual stresses (~100 – 200 MPa) near the edge of Cu ribbons after lamination. These stresses significantly reduce the fracture strength of the cells, highlighting the importance of accurate stress characterization for optimizing PV module manufacturing and performance.
研究不足
The study focuses on localized stresses around soldered Cu ribbons and may not fully represent the stress distribution in full-size modules. The analysis assumes isotropic material properties for silicon wafers, which may not account for anisotropy in actual conditions.
1:Experimental Design and Method Selection:
Utilized synchrotron X-ray microdiffraction (μSXRD) to characterize stress and fracture in crystalline silicon PV modules.
2:Sample Selection and Data Sources:
Standard generic design sc-Si solar cells of thickness
3:18 mm, with three busbars (3BB), were used. List of Experimental Equipment and Materials:
Synchrotron scanning X-ray microdiffraction setup at beamline
4:2 at the Advanced Light Source (ALS), Lawrence Berkeley National Laboratory. Experimental Procedures and Operational Workflow:
Samples were scanned from the backside of the cell, with a distance between each scanned point in X and Y directions of
5:1 mm and an exposure time of ~90 sec per point. Data Analysis Methods:
Crystal plane misorientation angles were used to calculate curvature and subsequently bending strains and stresses in the cell.
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