研究目的
To evaluate the applicability of a closed-path gas analyzer with two mid-infrared quantum cascade lasers (QCLs) for simultaneous measurement of nitrous oxide (N2O), methane (CH4) and carbon dioxide (CO2) fluxes from a cropland using the eddy covariance (EC) technique.
研究成果
The EC technique using a closed-path gas analyzer with two quantum cascade lasers is qualified for reliable and simultaneous measurements of N2O, CH4 and CO2 fluxes from a subtropical cropland throughout the year. Moreover, EC method based on this type of gas analyzer provides an additional option for long-term and simultaneous flux measurements of the three greenhouse gases in a wide range of agricultural and natural ecosystems.
研究不足
The study was conducted during the wintertime when the gas fluxes are at their lowest level in the year, which may not represent the full range of gas fluxes throughout the year. Additionally, the applicability of the EC system with a closed-path gas analyzer with two quantum cascade lasers for simultaneous measurements of N2O, CH4 and CO2 fluxes from other types of ecosystems was not evaluated.
1:Experimental Design and Method Selection:
The study evaluated the applicability of a closed-path gas analyzer with two mid-infrared quantum cascade lasers (QCLs) for simultaneous measurement of N2O, CH4 and CO2 fluxes from a cropland using the eddy covariance (EC) technique. A new approach was proposed to optimize the determination of lag times between the wind and gas concentration data.
2:Sample Selection and Data Sources:
Measurements were carried out in a typical vegetable field in the subtropical China during the wintertime, when the gas fluxes are at their lowest level in the year.
3:List of Experimental Equipment and Materials:
The dual-QCL analyzer showed a median precision (1σ) of 0.14 nmol mol?1 for N2O, 3.3 nmol mol?1 for CH4 and 0.36 μmol mol–1 for CO2 at sampling frequency of 10 Hz under the field conditions.
4:14 nmol mol?1 for N2O, 3 nmol mol?1 for CH4 and 36 μmol mol–1 for CO2 at sampling frequency of 10 Hz under the field conditions. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: The detection limit of the EC system for measuring half-hourly fluxes were 0.05 nmol m?2 s?1 for N2O, 1.12 nmol m?2 s?1 for CH4 and 0.14 μmol m–2 s–1 for CO
5:05 nmol m?2 s?1 for N2O, 12 nmol m?2 s?1 for CH4 and 14 μmol m–2 s–1 for COData Analysis Methods:
2. 5. Data Analysis Methods: The results showed that 100% of the N2O, 87% of the CH4 and 96% of the CO2 fluxes were larger than the above detection limits.
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