摘要： The concept of mixed 2D/3D heterostructures has emerged as an effective method in improving the stability of lead halide perovskite solar cells (PSCs), which is, however, rarely reported in lead-tin (Pb-Sn) mixed perovskite devices. Here, we report a scalable process for depositing mixed 2D/3D Pb-Sn perovskite solar cells that deliver remarkably enhanced efficiency and stability compared to their 3D counterparts. The incorporation of a small amount (3.75%) of an organic cation 2-(4-fluorophenyl)ethyl ammonium iodide (FPEAI) induces the growth of highly orientated Pb-Sn perovskite crystals perpendicularly aligned to the substrate. Moreover, for the first time, phase segregation is observed in pristine 3D Pb-Sn perovskite, which is suppressed due to the presence of the 2D perovskites. Accordingly, a high current density of 28.42 mA cm-2 is obtained due to markedly enhanced spectral response and charge extraction. Eventually, mixed 2D/3D Pb-Sn perovskite devices with a bandgap of 1.33 eV yield efficiencies as high as 17.51% and in parallel exhibit good stability.