研究目的
Investigating the synthesis and photoluminescence properties of Ca4La6(PO4)2(SiO4)4O2:Dy3+ phosphor for application in white light-emitting diodes.
研究成果
The Dy3+-activated CLPSO phosphors exhibit high thermal stability and suitable photoluminescence properties, making them promising candidates for near-UV white light-emitting diodes.
研究不足
The study focuses on the synthesis and properties of a specific phosphor, and its application is limited to white light-emitting diodes. Further optimization may be required for other applications.
1:Experimental Design and Method Selection:
High-temperature solid-state reaction method was used for synthesis. The crystal structure, diffuse reflection, photoluminescence, and photoluminescence excitation spectra, decay curves, as well as thermal stability were investigated.
2:Sample Selection and Data Sources:
Starting materials were CaCO3, La2O3, (NH4)H2PO4, SiO2, and Dy2O
3:List of Experimental Equipment and Materials:
X-ray diffractometer (Bruker D8 Advance), fluorescence spectrophotometer (Edinburgh FS5), UV/visible spectrophotometer (UV-3600, SHIMADZU), and spectrophotometer (Edinburgh Instruments, FLS980).
4:0). Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Materials were mixed, ground, preheated at 600 ℃ for 3 h, sintered at 1400 ℃ for 4 h, and then furnace-cooled.
5:Data Analysis Methods:
XRD patterns, PL, PLE, temperature-dependent luminescence spectra, and decay curves were analyzed.
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X-ray diffractometer
Bruker D8 Advance
Bruker
Obtaining powder X-ray diffraction patterns
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Fluorescence spectrophotometer
Edinburgh FS5
Edinburgh Instruments
Measuring PL, PLE, and temperature-dependent luminescence spectra
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UV/visible spectrophotometer
UV-3600
SHIMADZU
Measuring diffuse reflectance spectra
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Spectrophotometer
FLS980
Edinburgh Instruments
Obtaining decay curves
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