研究目的
Investigating the luminescence line broadening of CdSe nanoplatelets and quantum dots for application in white light LEDs (w-LEDs).
研究成果
The narrow bandwidth for core CdSe NPLs is attributed to a very narrow inhomogeneous linewidth, not stronger exciton-phonon coupling. Despite large thermal shifts, CdSe NPLs show superior spectral properties for application in w-LEDs and displays.
研究不足
The study is limited to CdSe nanostructures and does not explore other semiconductor materials. The high-temperature stability and color shift issues of NPLs for application in w-LEDs are noted as potential limitations.
1:Experimental Design and Method Selection:
Temperature dependent emission spectra of core and core-shell CdSe NPLs and QDs were recorded over a wide temperature range (4 to 423 K) to study contributions from homogeneous and inhomogeneous broadening.
2:Sample Selection and Data Sources:
CdSe QDs and NPLs of different sizes and shell thicknesses were synthesized. PL spectra were recorded using an Edinburgh FLS920 spectrometer.
3:List of Experimental Equipment and Materials:
Oxford Instruments liquid helium cryostat, Linkam high temperature stage, Hamamatsu R928 PMT detector, 450 W xenon lamp.
4:Experimental Procedures and Operational Workflow:
Emission spectra were corrected for the sensitivity of the detection system and converted to a photon flux per energy interval.
5:Data Analysis Methods:
The FWHM of the emission spectra was determined directly by measuring the spectral width at half the peak intensity.
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Hamamatsu R928 PMT detector
R928
Hamamatsu
Used for detecting emission spectra.
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Edinburgh FLS920 spectrometer
FLS920
Edinburgh
Used for recording PL spectra.
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Oxford Instruments liquid helium cryostat
Oxford Instruments
Used for temperature dependent measurements up to 300 K.
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Linkam high temperature stage
Linkam
Used for temperature dependent measurements above 300 K.
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450 W xenon lamp
Used as excitation source during measurements.
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