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Complementary cathodoluminescence lifetime imaging configurations in a scanning electron microscope

DOI:10.1016/j.ultramic.2018.11.006 期刊:Ultramicroscopy 出版年份:2018 更新时间:2025-09-23 15:21:01
摘要: Cathodoluminescence (CL) spectroscopy provides a powerful way to characterize optical properties of materials with deep-subwavelength spatial resolution. While CL imaging to obtain optical spectra is a well-developed technology, imaging CL lifetimes with nanoscale resolution has only been explored in a few studies. In this paper we compare three different time-resolved CL techniques and compare their characteristics. Two configurations are based on the acquisition of CL decay traces using a pulsed electron beam that is generated either with an ultra-fast beam blanker, which is placed in the electron column, or by photoemission from a laser-driven electron cathode. The third configuration uses measurements of the autocorrelation function g(2) of the CL signal using either a continuous or a pulsed electron beam. The three techniques are compared in terms of complexity of implementation, spatial and temporal resolution, and measurement accuracy as a function of electron dose. A single sample of InGaN/GaN quantum wells is investigated to enable a direct comparison of lifetime measurement characteristics of the three techniques. The g(2)-based method provides decay measurements at the best spatial resolution, as it leaves the electron column configuration unaffected. The pulsed-beam methods provide better detail on the temporal excitation and decay dynamics. The ultra-fast blanker configuration delivers electron pulses as short as 30 ps at 5 keV and 250 ps at 30 keV. The repetition rate can be chosen arbitrarily up to 80 MHz and requires a conjugate plane geometry in the electron column that reduces the spatial resolution in our microscope. The photoemission configuration, pumped with 250-fs 257-nm pulses at a repetition rate from 10 kHz to 25 MHz, allows creation of electron pulses down to a few ps, with some loss in spatial resolution.
作者: S. Meuret,M. Solà Garcia,T. Coenen,E. Kieft,H. Zeijlemaker,M. L?tzel,S. Christiansen,S.Y. Woo,Y-H Ra,Z. Mi,A. Polman
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To compare three different time-resolved cathodoluminescence (TR-CL) techniques in terms of complexity of implementation, spatial and temporal resolution, and measurement accuracy as a function of electron dose, using a single sample of InGaN/GaN quantum wells for direct comparison.

The study concludes that all three TR-CL techniques are complementary, with the choice of technique depending on the specific requirements for temporal resolution, spatial resolution, and acquisition time. The ultrafast blanker and laser-driven photocathode configurations offer detailed temporal dynamics, while the g(2)-based method provides superior spatial resolution without requiring a pulsed beam.

The study notes trade-offs between spatial and temporal resolution across techniques, with some configurations leading to lower spatial resolution for higher time-resolution. The accuracy of lifetime measurements varies with the technique, and the electron dose required for a given signal-to-noise ratio differs significantly between methods.

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