研究目的
Investigating the synthesis of silver nanoparticles using atmospheric-pressure pulsed discharge plasma in a slug flow system with and without the addition of starch as a stabilizer.
研究成果
Nonequilibrium atmospheric-pressure plasma was successfully applied in a slug flow reactor system to generate silver nanoparticles. The addition of starch as a stabilizer played a crucial role in preventing agglomeration and growth of silver nanoparticles, resulting in monodispersed nanoparticles with a spherical morphology and diameter less than 10 nm on average.
研究不足
The study did not present detailed information regarding the shape control mechanism for silver nanoparticle products. The effect of different types of starch was not investigated.
1:Experimental Design and Method Selection:
The experiment utilized a slug flow reactor system with pulsed discharge plasma to synthesize silver nanoparticles. Argon gas and silver nitrate solutions were used as the gas and liquid phases, respectively.
2:Sample Selection and Data Sources:
Silver nitrate (AgNO3) and starch were dissolved in distilled water to prepare the feed solution.
3:List of Experimental Equipment and Materials:
Glass capillary tube, liquid pump (HPLC, LC-10AD, Shimadzu Co., Japan), gas flow meter (RK-1250, Kofloc Instruments Inc., Japan), and AC power supply (TE-HVP1510K300-NP, Tamaoki Electronics Co. Ltd., Japan).
4:Experimental Procedures and Operational Workflow:
The feed solution and argon gas were flowed into the slug flow reactor system, and pulsed discharge plasma was applied.
5:Data Analysis Methods:
Optical emission spectroscopy, UV–vis spectroscopy, and transmission electron microscopy (TEM) were used to characterize the silver nanoparticles.
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UV–vis spectrophotometer
V-550
Jasco Corporation
Analyzing the absorbance spectrum of the aqueous solution products
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energy-dispersive X-ray spectroscopy
JED-2300T & Gatan, GIF Quantum ER
JEOL
Elemental characterization of particle products
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HPLC
LC-10AD
Shimadzu Co.
Pumping the feed solution into the slug flow reactor system
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digital oscilloscope
TDS2024C
Tektronix Inc.
Monitoring and measuring the breakdown voltage and current
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optical fiber spectrometer
OPwave+ HR4000
Ocean Optics
Spectral analysis during experiments
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gas flow meter
RK-1250
Kofloc Instruments Inc.
Measuring and controlling the flow rate of argon gas
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AC power supply
TE-HVP1510K300-NP
Tamaoki Electronics Co. Ltd.
Providing power to generate pulsed discharge plasma
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CCD camera
PI-MAX 512
Princeton Instruments
Capturing the distribution of optical emission intensity
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transmission electron microscopy
JEM-2100Plus
Japan Electronic Co., Ltd.
Characterizing the morphology and elemental maps of silver nanoparticle products
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Fourier transform infrared spectrophotometer
Spectrum Two
PerkinElmer Ltd.
Characterizing the starch before and after pulsed discharge plasma treatment
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