研究目的
To fabricate superhydrophobic micropillar array surface structures on transparent substrates using a straightforward two-step approach involving light-induced self-writing and spray coating with PTFE nanoparticles, aiming for scalable and tunable anti-wetting applications.
研究成果
The approach successfully fabricates superhydrophobic micropillar arrays with high transparency and mechanical durability. It offers a versatile, scalable method for anti-wetting surfaces, with potential applications in various fields. Future work could optimize pillar shapes and explore finer scales.
研究不足
The technique has constraints in resin thickness ranges for reliable pillar formation, potential pillar bending at larger heights, and variations in tip shape affecting wetting properties. Scale-up may require larger light sources or assembly of smaller units.
1:Experimental Design and Method Selection:
The study employs light-induced self-writing (LISW) with visible light photocuring to create micropillar arrays. A photomask generates periodic optical beams that induce self-focusing and pillar growth in a photo-crosslinking resin.
2:Sample Selection and Data Sources:
The resin is composed of trimethylolpropane triacrylate (TMPTA) with camphorquinone and a cationic initiator. Micropillar arrays are fabricated on transparent plastic substrates.
3:List of Experimental Equipment and Materials:
Equipment includes a blue LED light source, photomasks with specific aperture patterns, a spray coater, optical and scanning electron microscopes, and contact angle goniometers. Materials include TMPTA, PTFE nanoparticles, and photoinitiators.
4:Experimental Procedures and Operational Workflow:
The resin is poured into a cell, irradiated through a photomask for 20 minutes, washed to remove uncured monomer, dried, and spray-coated with PTFE nanoparticles. Wettability and durability tests are performed.
5:Data Analysis Methods:
Contact angles are measured using sessile drop and advancing/receding methods. SEM and optical microscopy are used for structural analysis. Data is analyzed for trends in hydrophobicity and transparency.
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blue LED light
λ_max = 470 nm
Thorlabs Inc.
Used as the light source for photocuring the resin, generating optical beams for self-writing.
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camera
Axiocam 105
Zeiss
Attached to the microscope for capturing images and videos of the samples.
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scanning electron microscope
JEOL JSM-5600
JEOL
Used for high-resolution imaging of the micropillar structures.
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optical microscope
Zeiss Axioscope
Zeiss
Used for imaging the micropillar arrays and capturing structural details.
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digital microscope
MicroView
Used for macro-lens imaging of droplets and surface wetting properties.
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contact angle goniometer
Ramé-Hart 250 F1
Ramé-Hart
Used for measuring water contact angles on the surfaces.
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VCA Optima system
AST Products
Used for advancing and receding contact angle measurements.
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spray coater
Used to apply a thin layer of PTFE nanoparticles onto the micropillar arrays.
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