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Computational and Experimental Investigation of Micro-Hardness and Wear Resistance of Ni-Based Alloy and TiC Composite Coating Obtained by Laser Cladding
摘要： The influence of processing parameters on the micro-hardness and wear resistance of a Ni-based alloy and titanium carbide (TiC) composite cladding layer was studied. Mathematical models were developed to predict the micro-hardness and wear resistance of the cladding layer by controlling the laser cladding processing parameters. Key processing parameters were the laser power, scanning speed, gas flow, and TiC powder ratio. The models were validated by analysis of variance and parameter optimization. Results show that the micro-hardness is positively correlated with laser power and TiC powder ratio, where the TiC powder ratio shows the most significant impact. The wear volume decreased with an increasing TiC powder ratio. The targets for the processing parameter optimization were set to 62 HRC for micro-hardness and a minimal volume wear. The difference between the model prediction value and experimental validation result for micro-hardness and wear volume were 1.87% and 6.33%, respectively. These models provide guidance to optimize the processing parameters to achieve a desired micro-hardness and maximize wear resistance in a composite cladding layer.
关键词： Ni35A + TiC composite,laser cladding,central composite design,wear resistance,micro-hardness
更新于2025-11-28 14:24:20
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Microstructure and properties of WC reinforced Ni-based composite coatings with Y <sub/>2</sub> O <sub/>3</sub> addition on titanium alloy by laser cladding
摘要： In this study, WC reinforced Ni-based composite coatings with Y2O3 addition were deposited on Ti-6Al-4V titanium substrate by laser cladding. The phases, microstructure, microhardness and wear resistance of the composite coatings were studied by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, microhardness tester and wear tester. The results showed that good metallurgical bonding was achieved between the composite coatings and substrate. The phases mainly were γ -Ni, TiC, TiB2, Ni3B, M23C6 and WC. Most of the WC was dissolved in small pieces of WC during the laser cladding process. The microhardness of the composite coatings was about 3 times that of the titanium substrate and the wear resistance of the composite coatings had a significant increase.
关键词： titanium alloy,microstructure,Laser cladding,Y2O3,WC,Ni-based composite coatings
更新于2025-11-28 14:24:20
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High-performance PZT-based Stretchable Piezoelectric Nanogenerator
摘要： Stretchable piezoelectric nanogenerators (SPNG) are highly desirable for power supply of flexible electronics. Piezoelectric composite material is the most effective strategy to render piezoelectric nanogenerators stretchable. However, the generated output performance is unsatisfactory due to the low piezoelectric phase proportion. Here we demonstrate a high-performance Pb(Zr0.52Ti0.48)O3 (PZT) -based stretchable piezoelectric nanogenerator (HSPG). The proposed HSPG exhibits excellent output performance with a power density of ~81.25μW/cm3, dozens of times higher than previously reported results. Mixing technique, instead of conventional stirring technology, is used to incorporate PZT particles into solid silicone rubber. The filler distribution homogeneity in matrix is thus remarkably improved, allowing higher filler composition. The PZT proportion in composite can be increased to 92wt% with satisfactory stretchability of 30%. Based on the excellent electrical and mechanical properties, the proposed HSPG can be attached to human body to harvest body kinetic energy with multiple deformation modes. The obtained energy can be used to operate commercial electronics or be stored into a capacitor. Therefore, our HSPG has great potential application in powering flexible electronics.
关键词： energy harvesting,PZT,Piezoelectric composite,stretchable nanogenerator
更新于2025-11-21 11:18:25
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Laser Welding of Dissimilar Metal Joint of 6061 Al Alloy and Al Matrix Composite
摘要： In this paper, dissimilar metal joints of 6061 aluminum alloy and aluminum matrix composite material are investigated by laser welding. TiB2 particles were added into the lap joint. The welding process, microstructure, and the corrosion properties of welding joints are examined. The results demonstrate that the selected optimization process parameters are laser power 6 kW, welding speed 0.6 mm/s, pulse width 11.5 ms, and laser frequency 4.5 Hz. There are a few obvious pores in the molten pool. Al2Ti, Fe2Si, and Al0.5Fe3Si0.5 are present in the microstructure. During the welding process, some TiB2 particles are decomposed and reacted with molten Al. Other TiB2 particles are nucleated and solidi?ed, and the excess TiB2 particles are pushed to the grain boundaries by molten Al. TiB2 particles are wetted well by molten matrix metal. The corrosion resistance of alloys in di?erent conditions decreased in the following order: the weld beam >6061 Al > AMC.
关键词： aluminum matrix composite,laser welding,TiB2 particles,microstructure,6061 aluminum alloy,dissimilar metal joints,corrosion properties
更新于2025-11-21 11:18:25
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Micropatterning MoS2/Polyamide Electrospun Nanofibrous Membranes Using Femtosecond Laser Pulses
摘要： The capability of modifying and patterning the surface of polymer and composite materials is of high significance for various biomedical and electronics applications. For example, the use of femtosecond (fs) laser ablation for micropatterning electrospun nanofiber scaffolds can be successfully employed to fabricate complex polymeric biomedical devices, including scaffolds. Here we investigated fs-laser ablation as a flexible and convenient method for micropatterning polyamide (PA6) electrospun nanofibers that were modified with molybdenum disulfide (MoS2). We studied the influence of the laser pulse energy and scanning speed on the topography of electrospun composite nanofibers, as well as the irradiated areas via scanning electron microscopy and spectroscopic techniques. The results showed that using the optimal fs-laser parameters, micropores were formed on the electrospun nanofibrous membranes with size scale control, while the nature of the nanofibers was preserved. MoS2-modified PA6 nanofibrous membranes showed good photoluminescence properties, even after fs-laser microstructuring. The results presented here demonstrated potential application in optoelectronic devices. In addition, the application of this technique has a great deal of potential in the biomedical field, such as in tissue engineering.
关键词： femtosecond laser,micromachining,composite nanofibers,electrospinning,MoS2
更新于2025-11-21 11:08:12
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Effects of TiO <sub/>2</sub> doping on microstructure and properties of directed laser deposition alumina/aluminum titanate composites
摘要： Al2O3-based composite ceramics have excellent high temperature performance and are ideal materials for preparing hot end components. However, poor fracture toughness and thermal shock resistance limit its applications. Based on the excellent low thermal expansion characteristics and thermal shock resistance of Al2TiO5 ceramic, different composition ratios of Al2O3/Al2TiO5 composite ceramics were prepared by directed laser deposition (DLD) technology. Effects of TiO2 doping amount on microstructure and properties of the composite ceramics were investigated. Results show that α-Al2O3 phase is discretely distributed in the continuous aluminum titanate matrix when TiO2 doping amount between 2 and 30 mol%. With the increase of TiO2 doping amount, content of Al2O3 gradually decreases and its morphology changes from cellular to dendritic. When TiO2 doping amount reaches 43.9 mol%, the microstructure transforms into fine Al2TiO5/Al6Ti2O13 eutectic structure. Property test results show that Al2O3/Al2TiO5 composite ceramics have good comprehensive mechanical properties when TiO2 doping amount between 2 and 6 mol%.
关键词： Al2O3/Al2TiO5,microstructure,Additive manufacturing,properties,composite ceramics
更新于2025-11-21 11:03:13
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Reusability and photocatalytic activity of bismuth-TiO2 nanocomposites for industrial wastewater treatment
摘要： In this study, bismuth-TiO2 nanotube (Bi-TNT) composites were used for the treatment of industrial wastewater. Bi-TNT were synthesized using two- and one-step anodization methods. The obtained composites were analyzed using X-ray diffraction, field emission scanning electron microscopy, UV–visible diffuse reflectance spectroscopy, Energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. For the two-step Bi-TNT composites, we investigated the effect of different Bi deposition times, Bi concentrations, and Bi deposition voltages on photodegradation efficiency. For the one-step Bi-TNT composites, we investigated the effect of different anodization voltages, anodization times, and Bi concentrations. Initially, the optimal synthesis conditions for two- and one-step Bi-TNT catalysts were identified and then these optimized conditions were used for industrial wastewater treatment that was collected from Banwol Sihwa Industrial Complex Republic of Korea. The Bi-TNT two- and one-step composites showed 2.0 and 2.5 times higher photocatalytic activity, respectively, for industrial wastewater treatment than that of TNT in visible-light. Recycling of Bi-TNT composites showed that the one-step composite method was more efficient and stable than the two-step method because Bi coupling and nanotube formation simultaneously occurred.
关键词： Recycling,Two- and one-step methods,Visible-light,Pollutant degradation,Bi-TiO2 composite
更新于2025-11-21 11:01:37
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Beta-lead oxide quantum dot (β-PbO QD)/polystyrene (PS) composite films and their applications in ultrafast photonics
摘要： Polymer composite films, particularly those based on polymers and layered nanomaterials, are attractive materials for exploiting the properties of multiple materials for applications in electronics and photonics. In this work, a beta-lead oxide quantum dot (β-PbO QD)/polystyrene (PS) composite film is successfully fabricated by a solution blending method. The β-PbO QDs are well-distributed within a β-PbO QD/PS composite film and the composite film is transparent and flexible. Owing to the almost complete insolubility of both β-PbO QDs and PS, the as-fabricated β-PbO QD/PS composite film holds the nonlinear photonic response from 540 nm to 1060 nm under complete water immersion, confirming its excellent stability to high humidity. Additionally, the β-PbO QD/PS composite film exhibits a considerable capacity for optical modulation owing to a strong nonlinear absorption coefficient compared with those of other two-dimensional (2D) materials. On the basis of a home-made β-PbO QD/PS composite film saturable absorber, stable mode-locked pulses at 1060 nm are generated under humid conditions. It is anticipated that the β-PbO QD/PS composite films enable the exploitation of new waterproof, flexible photonic devices based on functional 2D materials and polymers.
关键词： composite films,mode-locked pulses,ultrafast photonics,polystyrene,nonlinear absorption,beta-lead oxide quantum dot
更新于2025-11-19 16:56:42
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Electrolyte effects on formation and properties of PEDOT-graphene oxide composites
摘要： This work presents a comparative electrochemical and spectroelectrochemical study of composites consisting of poly(3,4-ethylenedioxythiophene) (PEDOT) and graphene oxide (GO) synthesized in different electrolyte solutions. The electrochemical behavior of PEDOT/GO composites were studied in an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) as well as in conventional organic (acetonitrile) and aqueous electrolytes by cyclic voltammetry and electrochemical impedance spectroscopy. Additionally, we applied in situ Attenuated Total Reflection Fourier Transformed Infrared (ATR–FTIR) spectroelectrochemistry using a Kretschmann geometry cell to study the composite fabrication during potentiodynamic electropolymerization, and to study the electronic properties and charge carrier formation during p-doping. According to in situ ATR-FTIR analysis, the doping induced bands from charge carrier formation begin to grow at lower potentials for the composite film and the electronic absorptions indicate formation of only one type of charge carrier in the composite made and characterized in ionic liquid. The optical properties during doping were determined by in situ UV–Vis spectroelectrochemistry. The composite film fabricated in water has its absorbance maximum at slightly higher wavelengths, and the appearance of the film is changed from well-known light blue color of PEDOT to greyish.
关键词： spectroelectrochemistry,PEDOT,composite,graphene oxide,electrolyte
更新于2025-11-19 16:56:35
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Adsorption and Photocatalytic Decomposition of Gaseous 2-Propanol Using TiO2-Coated Porous Glass Fiber Cloth
摘要： Combinations of TiO2 photocatalysts and various adsorbents have been extensively investigated for eliminating volatile organic compounds (VOCs) at low concentrations. Herein, TiO2 and porous glass cloth composites were prepared by acid leaching and subsequent TiO2 dip-coating of the electrically applied glass (E-glass) cloth, and its adsorption and photocatalytic ability were investigated. Acid leaching increased the specific surface area of the E-glass cloth from 1 to 430 m2/g while maintaining sufficient mechanical strength for supporting TiO2. Further, the specific surface area remained large (290 m2/g) after TiO2 coating. In the photocatalytic decomposition of gaseous 2-propanol, the TiO2-coated porous glass cloth exhibited higher adsorption and photocatalytic decomposition ability than those exhibited by the TiO2-coated, non-porous glass cloth. The porous composite limited desorption of acetone, which is a decomposition intermediate of 2-propanol, until 2-propanol was completely decomposed to CO2. The CO2 generation rate was affected by the temperature condition (15 or 35 °C) and the water content (2 or 18 mg/L); the latter also influenced 2-propanol adsorption in photocatalytic decomposition. Both the conditions may change the diffusion and adsorption behavior of 2-propanol in the porous composite. As demonstrated by its high adsorption and photocatalytic ability, the composite (TiO2 and porous glass cloth) effectively eliminates VOCs, while decreasing the emission of harmful intermediates.
关键词： air purification,composite,adsorption,microporous material,porous glass,photocatalyst,TiO2
更新于2025-11-19 16:51:07