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Ultra-sensitive method based on time-resolved fluorescence immunoassay for detection of sulfamethazine in raw milk
摘要： A novel lateral flow assay (LFA) was developed by introducing Eu (III)-doped polystyrene nanoparticles (EuNPs) for rapid and ultra-sensitive detection of sulfamethazine (SM2) in raw milk. The limit of detection and linear range of the proposed method were 0.0045 and 0.05–10 ng/mL, respectively. The recovery of LFA for the detection of SM2 in raw milk was 96.1–108.2%. The proposed LFA provides a rapid and convenient strategy for fast and ultra-sensitive screening of SM2 in raw milk. EuNP-LFA may be a remarkable method for the detection of other targets at low concentrations to ensure food safety.
关键词： Lateral flow assay,sulfamethazine,raw milk,Eu (III)-doped polystyrene nanoparticle
更新于2025-09-23 15:21:21
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[IEEE 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Chicago, IL, USA (2019.6.16-2019.6.21)] 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Toward >25% Efficient Monolithic Epitaxial GaAsP/Si Tandem Solar Cells
摘要： We report here on progress made in the development of >20% efficient monolithic epitaxial III-V/Si tandem solar cells. Following our prior demonstration of a GaAs0.75P0.25/Si tandem cell with verified AM1.5G efficiency of 20.1%, we have undertaken intensive efforts aimed at optimization of the top and bottom subcells, involving both materials quality improvement and detailed device structure refinement. To date we have thus demonstrated 21.8% AM1.5G GaAs0.75P0.25/Si tandem cells making use of an optimized, but still defect-limited GaAsP top cell combined with a simple diffusion-processed (emitter and back-surface field) Si bottom cell. With recent development of a low dislocation density III-V-on-Si epitaxial materials platform, as well as bottom cell enhancements for photon management, analytical performance loss analysis and efficiency projections indicate that >25% is achievable in the near-term, and 30% within reach with additional holistic optimization.
关键词： photovoltaic cells,Si,III-V semiconductor materials,semiconductor epitaxial layers
更新于2025-09-23 15:21:01
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[IEEE 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Chicago, IL, USA (2019.6.16-2019.6.21)] 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Hybrid III-V/SiGe solar cells on Si substrates and porous Si substrates
摘要： A tandem GaAsP/SiGe solar cell has been developed employing group-IV reverse buffer layers grown on silicon substrates with a subsurface porous layer. Reverse buffer layers facilitate a reduction in the threading dislocation density with limited thicknesses, but ease the appearance of cracks, as observed in previous designs grown on regular Si substrates. In this new design, a porous silicon layer has been incorporated close to the substrate surface. The ductility of this layer helps repress the propagation of cracks, diminishing the problems of low shunt resistance and thus improving solar cell performance. The first results of this new architecture are presented here.
关键词： tandem on silicon,porous silicon,reverse buffer layers,III-V on silicon,GaAsP/SiGe
更新于2025-09-23 15:21:01
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[IEEE 2019 Joint International EUROSOI Workshop and International Conference on Ultimate Integration on Silicon (EUROSOI-ULIS) - Grenoble, France (2019.4.1-2019.4.3)] 2019 Joint International EUROSOI Workshop and International Conference on Ultimate Integration on Silicon (EUROSOI-ULIS) - InAs Electron-Hole Bilayer LED
摘要： We report a novel switched-mode light-emitting device (LED) in an undoped ultra-thin body (UTB) InAs channel based on the electrostatically induced electron-hole (EH) bilayer concept. The induced EH channels at their respective gate interfaces, which remain spatially separated in steady state, gradually diffuse and recombine during a switch-off transient. Using TCAD simulations, we show that continuous switching of the gates with a ～ 12 μs time period leads to radiative recombination of the induced charge carriers with a peak internal quantum ef?ciency (IQE) as high as ～ 92%. The proposed concept obviates the need for chemically doped p-n junctions in the UTB device for light emitting applications and could also be employed for other direct bandgap semiconductors. However, the switching speed is ultimately limited by the thermal generation time.
关键词： ultra-thin body,thermal generation,light emission,Electrostatic doping,III-V on-insulator
更新于2025-09-23 15:21:01
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Novel cathode buffer layer of Al(acac)3 enables efficient, large area and stable semi-transparent organic solar cells
摘要： Electrode buffer layer plays a more crucial in semi-transparent organic solar cells (ST-OSCs) than that of the opaque devices due to the additional requirements of the average visible transmittance (AVT) and color rendering index (CRI) besides the power conversion efficiency (PCE). Herein, we developed a novel cathode buffer layer Aluminum(III) acetylacetonate (Al(acac)3) via mild spin-coating with post low temperature heat treatment process. Studies show that Al(acac)3 film possess outstanding optical features and suitable energy level. Namely, the absorption of Al(acac)3 film with thickness of 10 nm is as low as 1% and the transmittance is high up to 95% in the visible and near infrared regions, guarantying full absorption of the photoactive layer and high CRI for ST-OSCs; and the suitable energy level ensures a smooth electron transport and collection process. By introducing Al(acac)3 film in ST-OSCs, the devices based on PM6:Y6 yield an efficiency of 12.41%, an AVT of 25.33% (from 370 nm to 740 nm) and a CRI of 94.6. Encouragingly, the large-area ST-OSC of 100 mm2 with Al(acac)3 buffer layer yields an efficiency of 11.28%. Further long-term stability of ST-OSCs show that the device with encapsulation retains its 60% of the initial PCE over 60 hours continuous illumination. The results indicate that Al(acac)3 is a promising cathode buffer layer for fabricating efficient, large area and stable semi-transparent organic solar cells.
关键词： Semitransparent organic solar cells,cathode buffer layer,stability,Aluminum(III) acetylacetonate,large-area device
更新于2025-09-23 15:21:01
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Galliuma??Borona??Phosphide ($$\hbox {GaBP}_{2}$$): a new IIIa??V semiconductor for photovoltaics
摘要： Using machine learning (ML) approach, we unearthed a new III–V semiconducting material having an optimal bandgap for high-efficient photovoltaics with the chemical composition of Gallium–Boron–Phosphide (GaBP2, space group: Pna21). ML predictions are further validated by state-of-the-art ab initio density functional theory simulations. The stoichiometric Heyd–Scuseria–Ernzerhof bandgap of GaBP2 is noted to be 1.65 eV, a close ideal value (1.4–1.5 eV) to reach the theoretical Queisser–Shockley limit. The calculated electron mobility is similar to that of silicon. Unlike perovskites, the newly discovered material is thermally, dynamically and mechanically stable. Above all the chemical composition of GaBP2 is non-toxic and relatively earth abundant, making it a new generation of PV material. Using ML, we showed that with a minimal set of features, the bandgap of III–III–V and II–IV–V semiconductor can be predicted up to an RMSE of less than 0.4 eV. We have presented a set of scaling laws, which can be used to estimate the bandgap of new III–III–V and II–IV–V semiconductor, with three different crystal phases, within an RMSE of 0.4 eV.
关键词： Gallium–Boron–Phosphide,photovoltaics,GaBP2,III–V semiconductor,density functional theory,machine learning
更新于2025-09-23 15:21:01
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Synthesis of Calcium Aluminate-Based Luminophores by the Citrate Nitrate Sol–Gel Process
摘要： Microwave-assisted sol–gel process was used to synthesize calcium aluminate and luminescent materials based on it, which find wide use in the manufacture of construction materials, catalysts, optical emission sources, and display devices. The major processes involved in the formation of crystalline calcium aluminate were identified resorting to powder X-ray diffraction, thermal analysis, scanning electron microscopy, and IR spectroscopy data. Synthetic steps have moderate activation energies in the 44–260 kJ/mol range. Luminescence characteristics of the obtained crystal phosphors were measured. The increase in the synthesis temperature to 1200°C and the increase in the activator concentration to 5 mol % enhance the luminescence of the Eu3+-activated calcium aluminate-based luminophore. Further increase in the concentration of the activator ions leads to luminescence quenching caused by the concentration effect.
关键词： calcium aluminate,sol–gel process,microwave treatment,europium(III) ions,crystal phosphor
更新于2025-09-23 15:21:01
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Ancillary ligand increases the efficiency of heteroleptic Ir-based triplet emitters in OLED devices
摘要： The excellent contrast ratio, visibility, and advantages in producing thin and light displays let organic light emitting diodes change the paradigm of the display industry. To improve future display technologies, higher electroluminescence efficiency is needed. Herein, the detailed study of the non-radiative decay mechanism employing density functional theory calculations is carried out and a simple, general strategy for the design of the ancillary ligand is formulated. It is shown that steric bulk properly directed towards the phenylisoquinoline ligands can significantly reduce the non-radiative decay rate.
关键词： photoluminescence quantum yield,non-radiative decay,OLED,Ir(III)-complexes,density functional theory
更新于2025-09-23 15:21:01
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Cyclometalated Ir(III) Complexes Towards Blue-Emissive Dopant for Organic Light-Emitting Diodes: Fundamentals of Photophysics and Designing Strategies
摘要： The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09), and insufficient emission efficiency and stability. The latter problem is due to the highly energetic and hot excited states of these complexes, which yield faster decomposition. Therefore, control of the excited-state properties of cyclometalated Ir(III) complexes through systematic chemical modification of the ligands is being extensively investigated, with the aim of developing efficient and stable blue phosphorescent materials. The most common strategies towards achievement of a blue phosphorescent cyclometalated Ir(III) complex involve 1) substitution of electron-withdrawing F atoms at the cyclometalating ligands that stabilise the HOMO orbitals and 2) use of a heteropeltic system with electron-rich ancillary ligands bearing a 5-membered ring heterocycle to increase the LUMO energy level. However, the C–F bonds on the cyclometalating ligands have been found to be inherently unstable during device operation; thus, other types of electron-withdrawing groups (e.g., the cyano, trifluoromethyl, and sulfonyl groups) have been applied. Along with phosphorescence colour tuning to blue, the influence of the ligand structure on the photoluminescence quantum yield (PLQY) is also being intensively investigated. Two major PLQY lowering mechanisms for blue emissive Ir(III) complexes have been identified: 1) the vibronic-coupled non-radiative decay process and 2) crossing from the emissive state to an upper non-emissive 3MC excited state. To enhance the PLQY, mechanism 1) can be suppressed by employing rigid ligand frameworks to restrict intramolecular motion, whereas mechanism 2) can be prevented by destabilising the 3MC state using strong σ donor ligands such as N-heterocyclic carbenes. This review summarises the fundamental photophysics of cyclometalated Ir(III) complexes and surveys design strategies for efficient blue phosphorescent Ir(III) complexes, to provide a guide for future research in this field.
关键词： blue phosphorescent,3MC excited state,photoluminescence quantum yield,non-radiative decay,N-heterocyclic carbenes,cyclometalated Ir(III) complexes,OLEDs
更新于2025-09-23 15:21:01
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LITESEC-T3SS - Light-controlled protein delivery into eukaryotic cells with high spatial and temporal resolution
摘要： Many bacteria employ a type III secretion system (T3SS) injectisome to translocate proteins into eukaryotic host cells. Although the T3SS can efficiently export heterologous cargo proteins, a lack of target cell specificity currently limits its application in biotechnology and healthcare. In this study, we exploit the dynamic nature of the T3SS to govern its activity. Using optogenetic interaction switches to control the availability of the dynamic cytosolic T3SS component SctQ, T3SS-dependent effector secretion can be regulated by light. The resulting system, LITESEC-T3SS (Light-induced translocation of effectors through sequestration of endogenous components of the T3SS), allows rapid, specific, and reversible activation or deactivation of the T3SS upon illumination. We demonstrate the light-regulated translocation of heterologous reporter proteins, and induction of apoptosis in cultured eukaryotic cells. LITESEC-T3SS constitutes a new method to control protein secretion and translocation into eukaryotic host cells with unparalleled spatial and temporal resolution.
关键词： protein translocation,eukaryotic cells,optogenetics,type III secretion system,LITESEC-T3SS
更新于2025-09-23 15:21:01