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Synthesis and characterization of Ni incorporated titanium dioxide thin films
摘要： Thin ?lms of insulating Ti1(cid:1)xNixO2 (x 5 0.00, 0.05, 0.10, and 0.15) are synthesized by the spray pyrolysis technique. All the ?lms are seen to crystallize into polycrystalline anatase phase of TiO2. However, weak signature of the NiTiO3 phase is also observed for the ?lms having higher Ni ion concentration. Optical absorption analysis suggests nonmonotonous band gap decrease from 3.67 to 3.59 eV with respect to added concentration of Ni ions unto ‘x’ 5 0.10 in the TiO2 matrix. The presence of ferromagnetic ordering at room temperature in Ni incorporated TiO2 ?lms is revealed by M–H measurements. Calculated values of saturation magnetization indicate that the observed ferromagnetism is not due to the presence of Ni clusters or segregation of other ferromagnetic phase. Electrically insulating nature of the ?lms suggests that the observed FM ordering is most probably due to the ferromagnetic interaction between bound magnetic polarons which formed due to the creation of oxygen vacancies or defects.
关键词： ferromagnetism,Ni incorporated titanium dioxide,spray pyrolysis,optical properties,thin films
更新于2025-09-10 09:29:36
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Sensing of Acetone by Al-doped ZnO
摘要： The development of chemoresistive gas sensors for environmental and industrial air monitoring as well as medical breath analysis is investigated. Flame-made ZnO nanoparticles (NPs) doped with 1 at% Aluminum exhibited higher sensing performance (response 245, response time ~ 3 s, and sensitivity 23 ppm-1) than pure ZnO and those made by a hydrothermal method (HT) (56, ~ 12 s, and 4 ppm-1) for detection of 10 ppm acetone. Furthermore, their sensing response of ~10 to 0.1 ppm of acetone at 90% RH is superior to other metal oxide sensors and they feature good acetone selectivity to other compounds (including NH3, isoprene and CO). Characterization by N2 adsorption, X-ray photoelectron and UV-vis spectroscopies reveals that the improved sensing performance of flame-made Al-doped ZnO NPs is associated primarily to a higher density of oxygen vacancies than pure ZnO and all HT-made NPs. This leads to a greater number of adsorbed oxygen ions on the surfaces of Al-doped ZnO NPs, which can react with acetone molecules.
关键词： nanoparticles,flame spray pyrolysis,Al-doped ZnO,acetone,gas sensors
更新于2025-09-10 09:29:36
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Effect of Cadmium Dopant on Structure and Optical Properties of ZnO Thin Films Prepared by Spray Pyrolysis Technique
摘要： Effect of Cadmium Dopant on Structure and Optical Properties of ZnO Thin Films Prepared by Spray Pyrolysis Technique
关键词： Spray Pyrolysis Technique,Optical Properties,ZnO Thin Films,Cadmium Dopant
更新于2025-09-10 09:29:36
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Impact of molarity on structural, optical, morphological and electrical properties of copper oxide thin films prepared by cost effective jet nebulizer spray pyrolysis technique
摘要： Copper oxide (CuO) thin films were prepared by simple and cost effective jet nebulizer spray pyrolysis method with different molar concentration 0.1, 0.2 and 0.3 M named as J1, J2 and J3 respectively. The impact of molarity on structural, optical, morphological and electrical of properties of CuO thin film was studied. The structural studies confirmed that the prepared CuO thin films are monoclinic crystal structure matching with standard JCPDS card No. 89-5899. The thickness of CuO thin films determined by surface profilometer found to be increasing while increasing molar concentration. The optical energy band gaps were determined using Kulbelka–Munk (K–M) method are found to be 2.1 eV, 1.9 eV and 1.8 eV for J1, J2 and J3 respectively. The morphological properties and chemical composition of CuO thin film were investigated via field-emission scanning electron microscope (FESEM) and energy dispersive analysis from X-ray spectroscopy (EDAX). According to FESEM all the prepared CuO thin films are well covered and adhered to the substrate with good homogeneity and EDAX spectra confirms the presence of copper (Cu) and oxygen (O). The adhesion strength has been determined in accordance with test method D3330 using scotch tape test. The electrical conductivity of CuO thin films were investigated. The maximum conductivity value of the CuO thin film is observed 2.75 × 10?8 S/cm.
关键词： Thin films,Molar concentration,Copper oxide,Morphological properties,Jet nebulizer spray pyrolysis,Structural properties,Optical properties,Electrical properties
更新于2025-09-09 09:28:46
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Flame spray pyrolysis synthesized gold-loaded titanium dioxide photocatalyst for degradation of Rhodamine B
摘要： Gold-loaded titanium dioxide (Au-loaded TiO2) was synthesized by the flame spray pyrolysis method for using as photocatalyst. The synthesized Au-loaded TiO2 photocatalyst was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The photocatalytic degradation of Rhodamine B (RhB) dye solution over synthesized Au-loaded TiO2 was studied. The concentration of RhB was determined by UV–Vis spectrophotometry. For the photocatalytic activity, it was found that Au(1.00 mol%)-loaded TiO2 was a better photocatalyst than others under the same reaction conditions. The optimal conditions for photocatalytic degradation of RhB were found to be 0.6 g/L of photocatalyst concentration under UV light irradiation (UV–C 254 nm). The highest kinetic rate constant of photocatalyst was 0.0057 min?1 at the optimum conditions and the mechanism of the photocatalytic process had also been discussed.
关键词： Rhodamine B,Flame spray pyrolysis,Au-loaded TiO2,Degradation,Photocatalyst
更新于2025-09-09 09:28:46
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Effect of Aluminium doping on photoluminescence and third-order nonlinear optical properties of nanostructured CdS thin films for photonic device applications
摘要： The work presented here reports the influence of Aluminium (Al) doping on CdS thin films for the structural, morphological, optical and third-order nonlinear optical (NLO) properties. Thin films of Pure CdS and Al-doped CdS (Cd1-xAlxS) with x= 0, 0.01, 0.05 and 0.1 are prepared on the glass substrate at 350oC using the spray pyrolysis technique. The observed X-Ray Diffraction (XRD) patterns of CdS films are found to a polycrystalline hexagonal structure and are not much affected by Al doping. Also the films have been examined by Field Emission Scanning Electron Microscopy (FESEM) images. The transmittance of the CdS films is observed to be 50 to 60% in the visible region and that decreased at higher doping concentrations and with higher Al doping the direct optical band gap is decreased from 2.52 to 2.38 eV. To understand the defect states characteristics, the corresponding room-temperaturephotoluminescence (RTPL) spectra have also been taken and found the nonlinear behavior in a band to band-edge emission in the prepared samples upon Al incorporation. The sign and the magnitude of the third-order NLO properties were determined using the Z-scan technique with a continuous wave laser as the excitation source. It is observed that the material exhibit strong two-photon absorption (2PA) with the nonlinear absorption (NLA) coefficient (β) in the range of 10-4 cmW-1 and nonlinear refractive index (NRI) n2 ~10-9 cm2W-1. The third-order NLO susceptibility has found to be enhanced from 3.12 x10-5 esu to 6.36 x10-5 esu upon Al incorporation. Optical limiting characteristics of the prepared films are studied at the experimental wavelength. The results suggest that the Cd1-xAlxS is a promising material for nonlinear optical devices at 532 nm and optical power limiting applications.
关键词： photoluminescence,spray pyrolysis,Al-doped CdS thin films,Z-scan,structural,nonlinear optical properties
更新于2025-09-09 09:28:46
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[IEEE 2018 International Semiconductor Conference (CAS) - Sinaia, Romania (2018.10.10-2018.10.12)] 2018 International Semiconductor Conference (CAS) - Comparative Study of the Electrical Properties of CZTS-TiO2 and CZTS-ZnO Heterojunctions for PV Applications
摘要： Two heterojunctions based on Cu2ZnSnS4 were obtained as thin films, on FTO glass, by spray pyrolysis deposition. The choice of the n-type layer (TiO2 or ZnO) has impacted the nucleation and growth of the CZTS layers deposited on top. Crystalline thin films were obtained with drastically different morphologies. Small spherical grains promoted a better match at the interface between TiO2 and CZTS, while the hexagonal plates of ZnO promoted discontinuations. Both junctions proved photosensitive and gave good rectifying behavior but efficiencies charge than recombination at the interface or in the CZTS layer. suggest 0.01% lower
关键词： spray pyrolysis deposition,CZTS-based heterojunctions,interface,curent-voltage variation
更新于2025-09-09 09:28:46
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Growth and Structural Properties of Graphene Oxide Thin Film with Spray Pyrolysis Technique
摘要： The spray pyrolysis technique (SPT) is one of the most useful and simple methods to grow graphene oxide (GO) thin film. Good-quality GO thin films were fabricated by spray coating with GO powder (prepared by the modified Hummers method) on glass substrates. Raman spectroscopy, Field Emission Scanning Electron Microscope (FESEM), X-ray diffraction (XRD) analysis, and UV–visible spectroscopy were done to observe the presence of functional groups in the growth thin films and to determine the structure of GO. From the result of XRD test, the GO demonstrates peak at 10.58°(2θ), while the Raman spectroscopy reveals the presence of two prominent peaks, known as D and G bands, as well as 2D band. The ID/IG ratio for spray-deposited GO film was calculated with the value of 0.84. FESEM images showed that the glass substrates were completely covered by GO at different magnifications with a sheet-like structure. The optical absorption of graphene oxide was also observed at a wavelength rang of 275-350 nm.
关键词： Graphene Oxide,Thin Film,Spray Pyrolysis Technique,Structural Properties
更新于2025-09-04 15:30:14
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AIP Conference Proceedings [Author(s) 4TH ELECTRONIC AND GREEN MATERIALS INTERNATIONAL CONFERENCE 2018 (EGM 2018) - Bandung, Indonesia (27–28 July 2018)] - Physical investigations of nano and micro lithium-niobate deposited by spray pyrolysis technique
摘要： In this paper, lithium-niobate thin films were deposited using spray pyrolysis method. Further investigations of the physical properties of prepared samples were also studied. The spray pyrolysis deposition method was performed over a quartz substrate employing new raw materials as precursor compounds. During the deposition process, a range of annealing temperatures were set to maintain a physical changes in the prepared samples properties. Further, the structural properties were also characterized using field emission scanning electron microscope (FE-SEM), AFM, and film thickness.
关键词： structural properties,Spray pyrolysis,Lithium-Niobate,morphological properties
更新于2025-09-04 15:30:14
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Effect of doping Fe/Cu/Ti on WO <sub/>3</sub> on furfural degradation
摘要： This research improved tungsten oxide catalysts to increase efficiency in photocatalytic degradation of furfural under visible light. The aim of this research was to compare the efficiency of modified tungsten oxide with undoped and commercial tungsten oxide. Tungsten oxide nanoparticles were doped with 3 single metals, which were Fe/Cu/Ti at 1%wt, 2%wt, and 3%wt, synthesized by flame spray pyrolysis technique (FSP) and then characterization by X-Ray Diffraction (XRD), N2 adsorption/desorption (BET surface area analysis), UV-Vis Spectroscopy (UV-Vis). Photocatalytic degradation experiments using doped WO3 were carried out with 5 ppm initial concentration of furfural solution using 0.6 M catalyst concentration under visible light. From the results, FSP-synthesized WO3 has better efficiency in furfural degradation than the commercial WO3. All catalysts have mesoporous structure because an average pore size is in the range of 6-10 nm. Among all synthesized and doped WO3, it can be concluded that 3%wt Fe-doped tungsten oxide provides the highest acceleration rate in photocatalytic degradation of furfural.
关键词： furfural,photocatalytic degradation,flame spray pyrolysis,tungsten oxide,doping
更新于2025-09-04 15:30:14