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Conductive treatment of Piezoelectric Composite Material by low-temperature adhesion comparing with ion sputtering
摘要： The surface conductive treatment is an essential step for piezoelectric composite material being application, but until now there are many issues remain to be solved. A conductive adhesion with low curable temperature, low resistivity and high welding spot adhesion strength was obtained for the conductive treatment of piezoelectric composite material. The welding spot adhesion strength was defined at first time. The conductive and adhesion properties were studied comparing with samples treated by ion sputtering. The conductive adhesive with curing agent of EDA has the lowest resistivity of 1.973× 10-4 Ω·cm and the highest welding spot adhesion strength of 7.93MPa.
关键词： Surface conductive treatment,Silver compounds,Adhesive,Piezoelectric Composites
更新于2025-11-21 11:18:25
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Self-generating CeVO4 as conductive channel within CeO2/CeVO4/V2O5 to induce Z-scheme-charge-transfer driven photocatalytic degradation coupled with hydrogen production
摘要： The construction of highly efficient Z-scheme photocatalytic system is regarded as a hot research topic in the fields of environmental remediation and renewable energy production. In this work, a novel Z-scheme CeO2/CeVO4/V2O5 photocatalyst is successfully prepared by using solid phase reaction method. The photocatalytic degradation of organic pollutant (Methylene Blue) with simultaneous hydrogen production is efficiently realized over the prepared Z-scheme CeO2/CeVO4/V2O5 photocatalysts under visible-light irradiation. The effects of treatment temperatures and treatment times of CeO2/V2O5 composite on the photocatalytic performance of Z-scheme CeO2/CeVO4/V2O5 photocatalyst are studied. The as-prepared Z-scheme CeO2/CeVO4/V2O5 (550-3) photocatalyst heat-treated at 550 °C for 3.0 h exhibits the highest photocatalytic performance. It can be ascribed to a moderate amount of CeVO4 nanoparticles generated between CeO2 and V2O5. The generated CeVO4 nanoparticles can be used as effective conductive channel to transfer the photo-generated carriers. At the same time, as redox reaction centers it can further accelerate the transfer of photo-generated electrons, effectively enhancing the separation efficiency of photo-generated electron and hole pairs. Furthermore, cyclic test demonstrates that the as-prepared Z-scheme CeO2/CeVO4/V2O5 (550-3) photocatalyst still maintains a high level of photocatalytic activity within five periods under the same conditions. Moreover, the related photocatalytic mechanism for degradation of organic pollutants with simultaneous hydrogen evolution over the Z-scheme CeO2/CeVO4/V2O5 (550-3) photocatalyst is proposed. Perhaps, this study affords a simple and novel method to design and develop next generation of highly efficient Z-scheme photocatalysts.
关键词： Conductive channel,Z-scheme CeO2/CeVO4/V2O5 photocatalyst,Solid phase reaction method,Simultaneous hydrogen evolution,Visible-light photocatalytic degradation
更新于2025-11-19 16:51:07
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Matrix-Independent Highly Conductive Composites for Electrodes and Interconnects in Stretchable Electronics
摘要： Electrically conductive composites (ECCs) hold great promise in stretchable electronics due to their printability, facile preparation, elasticity, and possibility for large area fabrication. A high conductivity at steady state and during mechanical deformation is a critical property for ECCs, and extensive efforts have been made to improve the conductivity. However, most of those approaches are exclusively functional to a specific polymer matrix, restricting their capability to meet other requirements such as the mechanical, adhesive and thermomechanical properties. Here we report a generic approach to prepare ECCs with conductivity close to that of bulk metals and maintain their conductivity during stretching. This approach iodizes the surfactants on the commercial silver flakes, and subsequent photo exposure converts these silver iodide nanoparticles to silver nanoparticles. The ECCs based on silver nanoparticles-covered silver flakes exhibit high conductivity because of the removal of insulating surfactants as well as the enhanced contact between flakes. The treatment of silver flakes is independent of the polymer matrix and provides the flexibility in matrix selection. In the development of stretchable interconnects, ECCs can be prepared with the same polymer as the substrate to ensure strong adhesion between interconnects and the substrate. For the fabrication of on-skin electrodes, a polymer matrix of low modulus can be selected to enhance conformal contact with the skin for reduced impedance.
关键词： conductive composites,human-machine interface,on-skin electronics,electrophysiological monitoring,iodization,silver nanoparticles,silver flakes
更新于2025-11-14 17:28:48
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Nondestructive nanofabrication on monocrystalline silicon via site-controlled formation and removal of oxide mask
摘要： A nondestructively patterned silicon substrate serves as an ideal support for forming high-quality optical structures or devices. A new approach was proposed for fabricating site-controlled structures without destruction on a monocrystalline silicon surface via local anodic oxidation (LAO) and two-step postetching. The nondestruction was demonstrated by conductivity detection with conductive atomic force microscopy (AFM), and an almost perfect crystal lattice was observed from the fabricated hillock by high-resolution transmission electron microscopy (HRTEM). By programming AFM tip traces for LAO processing, site-controlled nondestructive patterns with di?erent layouts can be produced. This approach provides a new route for realizing nondestructive optical substrates.
关键词： conductive atomic force microscopy,high-resolution transmission electron microscopy,local anodic oxidation,nondestructive nanofabrication,monocrystalline silicon
更新于2025-11-14 17:04:02
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Interface modified flexible printed conductive films via Ag <sub/>2</sub> O nanoparticle decorated Ag flake inks
摘要： A new approach to stable, low resistance inexpensive printed flexible conductive inks is proposed. Silver inks have been extensively studied and commercialized for applications in printed electronics due to the inherent high conductivity and stability of silver, even in particulate-based percolation networks processed at temperatures compatible with low cost polymer films such as polyethylene terephthalate (PET). Recent interest in flexible and even stretchable circuits, however, has presented new challenges for particle-based inks as mechanical strains can result in the opening of critical particle-to-particle contacts. Here we report a facile, low cost method for the single step synthesis of stable, printable nanoscale Ag2O-decorated Ag flake inks which can be converted to highly conductive Ag films at 150°C curing temperature without the use of limited shelf life organometallics or low metal loading nanoparticles to modify the interface between silver flakes. Analysis indicate that decoration of Ag flakes with Ag2O nanoparticles (NPs) during ink synthesis improves the conductivity and flexibility of printed silver films by forming bridging interconnections between Ag flakes after low temperature reduction of the Ag2O NPs. In this work, printed nano-decorated silver conductors with starting oxide to metal weight ratios of 5:95 exhibited lateral resistivities lower than 1.5×10-5 ? cm, which was 35% less than films derived from undecorated Ag flake inks of the same total Ag loading and binder system. This resistivity difference increased to 45% after cyclic bend testing showing increased resilience to repeated flexing for the nano-decorated inks. Through detailed compositional and morphological characterizations, we demonstrate that such improved conductivity and flexibility is due to a more effective bridging afforded by the in-situ synthesized Ag NPs on the surface of Ag flakes. These properties, combined with the simplified syntheses method of the nano-ink, make the material a viable, advantageous alternative to the limited number of stretchable conductors currently available.
关键词： Ag2O nanoparticle-decorated Ag flake inks,printed conductive films,interface modification,silver ink
更新于2025-11-14 17:04:02
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Solubilization of Carbon Nanotubes with Ethylene-Vinyl Acetate for Solution-Processed Conductive Films and Charge Extraction Layers in Perovskite Solar Cells
摘要： Carbon nanotube (CNT) solubilization via non-covalent wrapping of conjugated semiconducting polymers is a common technique used to produce stable dispersions for depositing CNTs from solution. Here, we report the use of a non-conjugated insulating polymer, ethylene vinyl acetate (EVA), to disperse multi- and single-walled CNTs (MWCNT and SWCNT) in organic solvents. We demonstrate that despite the insulating nature of the EVA, we can produce semitransparent films with conductivities of up to 34 S/cm. We show, using photoluminescence spectroscopy, that the EVA strongly binds to individual CNTs, thus making them soluble, preventing aggregation, and facilitating the deposition of high-quality films. To prove the good electronic properties of this composite, we have fabricated perovskite solar cells using EVA/SWCNTs and EVA/MWCNTs as selective hole contact, obtaining power conversion efficiencies of up to 17.1%, demonstrating that the insulating polymer does not prevent the charge transfer from the active material to the CNTs.
关键词： perovskite solar cells,carbon nanotubes,insulating polymer,conductive films,CNT polymer functionalization
更新于2025-11-14 15:25:21
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Aluminum-Doped Zinc Oxide as Front Electrode for Rear Emitter Silicon Heterojunction Solar Cells with High Efficiency
摘要： Transparent conductive oxide (TCO) layers of aluminum-doped zinc oxide (ZnO:Al) were investigated as a potential replacement of indium tin oxide (ITO) for the front contact in silicon heterojunction (SHJ) solar cells in the rear emitter configuration. It was found that ZnO:Al can be tuned to yield cell performance almost at the same level as ITO with a power conversion efficiency of 22.6% and 22.8%, respectively. The main reason for the slight underperformance of ZnO:Al compared to ITO was found to be a higher contact resistivity between this material and the silver grid on the front side. An entirely indium-free SHJ solar cell, replacing the ITO on the rear side by ZnO:Al as well, reached a power conversion efficiency of 22.5%.
关键词： photovoltaics,silicon heterojunction,rear emitter,transparent conductive oxide
更新于2025-11-14 15:25:21
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Fabrication of conductive fibrous scaffold for photoreceptor differentiation of mesenchymal stem cell
摘要： Conductive nanofibrous scaffolds with that can conduct electrical current have a great potential in neural tissue engineering. The purpose of this study was to survey effects of electrical stimulation and polycaprolactone/polypyrrole/multiwall carbon nanotube (PCL/PPY/MWCNTs) fibrous scaffold on photoreceptor differentiation of trabecular meshwork mesenchymal stem cells (TM‐MSCs). PCL/PPY/MWCNTs scaffold was made by electrospinning method. TM‐MSCs were seeded on PCL/PPY/MWCNTs scaffold and stimulated with a potential of 115 V/m. Scanning electron microscopy, transmission electron microscopy, and FT‐IR were used to evaluate the fabricated scaffold. Immunofluorescence and quantitative real‐time polymerase chain reaction were used to examine differentiated cells. Scanning electron microscopy, transmitting electron microscopy, and FT‐IR confirmed the creation of the composite structure of fibers. RT‐qPCR analysis showed that the expression of rhodopsin and peripherin genes in electrically stimulated cells were significantly higher (5.7‐ and 6.23‐fold, respectively; p ≤ 0.05) than those with no electrical stimulation. Collectively, it seems that the combination of PCL/PPY/MWCNTs scaffold, as a suitable conductive scaffold, and electrical stimulation could be an effective approach in the differentiation of stem cells in retinal tissue engineering.
关键词： electrical conductive,trabecular meshwork mesenchymal stem cells,photoreceptor‐like cells,nanostructure
更新于2025-11-14 15:18:02
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Effect of front TCO on the performance of rear-junction silicon heterojunction solar cells: Insights from simulations and experiments
摘要： In this study we make a detailed comparison between indium tin oxide (ITO), aluminum-doped zinc oxide (ZnO:Al) and hydrogenated indium oxide (IO:H) when applied on the illuminated side of rear-junction silicon heterojunction (SHJ) solar cells. ITO being the state of the art material for this application, ZnO:Al being an attractive substitute due to its cost effectiveness and IO:H being a transparent conductive oxide (TCO) with high-mobility and excellent optical properties. Through numerical simulations, the optically optimal thicknesses for a double layer anti-reflective coating system, consisting of the respective TCO and amorphous silicon oxide (a-SiO2) capping layers are defined. Through two-dimensional electrical simulations, we present a comparison between front-junction and rear-junction devices to show the behavior of series resistance (Rs) in dependence of the TCO sheet resistance (Rsh) and the device effective lifetime (τeff). The study indicates that there is a τeff dependent critical TCO Rsh value, above which, the rear-junction device will become advantageous over the front-junction design in terms of Rs. Solar cells with the respective layers are analyzed. We show that a thinner TCO optimized layer will result in a benefit in cell performance when implementing a double layer anti-reflective coating. We conclude that for a highest efficiency solar cell performance, a high mobility TCO, like IO:H, is required as the device simulations show. However, the rear-junction solar cell design permits the implementation of a lower conductive TCO in the example of the cost-effective ZnO:Al with comparable performance to the ITO, opening the possibility for substitution in mass production.
关键词： Transparent conductive oxide,Sheet resistance,Series resistance,Rear-junction,Silicon heterojunction,Anti-reflective coating
更新于2025-10-22 19:40:53
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Nanostructured Transparent Conductive Electrodes for Applications in Harsh Environments Fabricated via Nanosecond Laser‐Induced Periodic Surface Structures (LIPSS) in Indium–Tin Oxide Films on Glass
摘要： A self-organization phenomenon named laser-induced periodic surface structures (LIPSS) is utilized for pattern formation in indium–tin oxide (ITO) transparent conductive films coated on borosilicate glass. Stripe patterns with periodicities down to 175 nm are created by scanning the focused beam (30 μm spot diameter 1 e?2) of a nanosecond pulsed laser operating at 532 nm wavelength over ITO films. Highly ordered ITO-LIPSS are generated at a pulse duration of 6 ns, pulse frequencies between 100 and 200 kHz, pulse energies around 20 μJ, and laser spot scan speeds in the range of 50–80 mm s?1. Resulting nanopatterns are electrically conductive and feature improved optical transparency as well as stability against strong acids such as hydrochloric acid, sulfuric acid, and even aqua regia. The formation of mixed phases between ITO and silicon is considered to be the origin for the chemical robustness of laser patterned transparent conductive electrodes.
关键词： laser-induced periodic surface structures (LIPSS),laser patterning,self-organization,indium–tin oxide (ITO),transparent conductive films (TCF)
更新于2025-10-22 19:40:53