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Structural and electrical properties of Gd-doped BiFeO3:BaTiO3 (3:2) multiferroic ceramic materials
摘要： Gadolinium doped BiFeO3:BaTiO3 (3:2) polycrystalline multiferroic ceramics have been prepared by high-temperature solid state reaction technique. X-ray diffraction (XRD) analysis at room temperature of the prepared materials confirmed the formation of the compounds with rhombohedral crystal structure. The average particle size of as prepared samples have been found in the range of 35 nm to 55 nm for different doping concentrations. The average grain size of as prepared samples are less than 100 nm which is confirmed from SEM study. The SEM of annealed compounds showed the uniform distribution of grains and the formation of dense ceramic with average grain size in the order of 4 μm. Dielectric studies of the materials reveals that the dielectric constant ( εr ) and tangent loss (tan δ) decreases with doping concentrations at room temperature. The variation of εr and tan δ with temperature was explained on the basis of Maxwell–Wagner mechanism. The values of grain resistance ( Rb ) and grain capacitance (Cb) were obtained from Nyquist plots for the different doping concentrations at 300 °C. The activation energy ( Ea ) was calculated from the curve of frequency dependent ac conductivity ( σac ) within the range 0.19 eV to 0.45 eV. The remnant polarization of the samples (0.53 μC/cm2) was measured from polarization versus electric field (P–E) hysteresis curves. The ferromagnetic behaviour of the Gd-doped BiFeO3:BaTiO3 (3:2) sample has been studied by SQUID for the lowest doping concentration. The value of remnant magnetization was found 0.0235 emu/g at room temperature.
关键词： multiferroic ceramics,dielectric properties,ferroelectric properties,Gd-doped BiFeO3:BaTiO3,ferromagnetic properties
更新于2025-09-09 09:28:46
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Dielectric, electrical and impedance study of single perovskite Pb(Ni1/3Mn1/3W1/3)O3
摘要： A multiferroic material Pb(Ni1/3Mn1/3W1/3)O3 with ferroelectric and ferromagnetic properties at room temperature is designed for multifunctional applications. A orthorhombic perovskite crystal structure has been assigned for the present perovskite according to the X-ray diffraction patterns. At 1 kHz, dielectric constant (er) increases from 1655 at 298 K to its ?rst maximum 3514 at 457 K referred as magnetic transition. The high values of er in the low frequency range show better dispersion, and with the increase in frequency, a gradual decrease in the er values was observed. The contribution of grain and/or electrode/interface effects in the resistive/capacitive properties was ascertained by the Nyquist plots. An equivalent circuit has been suggested consisting of resistive and capacitive components (R, C, Q) estimates the bulk (grain) and grain boundary resistance and capacitance. The activation energy was found to be greater than 0.2 eV, supporting the conduction mechanism due to hopping of charge carriers.
关键词： Solid-state reaction,Multiferroic material,Dielectric response,Electrochemical impedance spectroscopy,Ceramics
更新于2025-09-09 09:28:46
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Composition-dependent xBa(Zr0.2Ti0.8)O3-(1-x)(Ba0.7Ca0.3)TiO3 bulk ceramics for high energy storage applications
摘要： This work reports the composition dependent microstructure, dielectric, ferroelectric and energy storage properties, and the phase transitions sequence of lead free xBa(Zr0.2Ti0.8)O3-(1-x)(Ba0.7Ca0.3)TiO3 [xBZT-(1-x)BCT] ceramics, with x = 0.4, 0.5 and 0.6, prepared by solid state reaction method. The XRD and Raman scattering results confirm the coexistence of rhombohedral and tetragonal phases at room temperature (RT). The temperature dependence of Raman scattering spectra, dielectric permittivity and polarization points a first phase transition from ferroelectric rhombohedral phase to ferroelectric tetragonal phase at a temperature (TR-T) of 40 0C and a second phase transition from ferroelectric tetragonal phase - paraelectric pseudocubic phase at a temperature (TT-C) of 110 0C. The dielectric analysis suggests that the phase transition at TT-C is of diffusive type and the BZT-BCT ceramics are a relaxor type ferroelectric materials. The composition induced variation in the temperature dependence of dielectric losses was correlated with full width half maxima (FWHM) of A1, E(LO) Raman mode. The saturation polarization (Ps) ≈ 8.3 μC/cm2 and coercive fields ≈ 2.9 kV/cm were found to be optimum at composition x = 0.6 and is attributed to grain size effect. It is also shown that BZT-BCT ceramics exhibit a fatigue free response up to 105 cycles. The effect of a.c. electric field amplitude and temperature on energy storage density and storage efficiency is also discussed. The presence of high TT-C (110 0C), a high dielectric constant (εr ≈ 12285) with low dielectric loss (0.03), good polarization (Ps) ≈ 8.3 μC/cm2) and large recoverable energy density (W = 121 mJ/cm3) with an energy storage efficiency (η) of 70 % at an electric field of 25 kV/cm in 0.6BZT-0.4BCT ceramics make them suitable candidates for energy storage capacitor applications.
关键词： spontaneous polarization,Raman spectroscopy,dielectric constant,lead free ceramics,Energy storage capacitors,fatigue
更新于2025-09-09 09:28:46
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Ultrapure NIR-to-NIR Single Band Emission of β-PbF2: Yb3+/Tm3+ in Glass Ceramics
摘要： An ultrapure near infrared (NIR) emission entered at 800 nm upon 976 nm laser excitation (NIR-to-NIR) was observed in β-PbF2: Yb3+/Tm3+ glass ceramics (GCs). The ultrapure NIR-to-NIR single band emission originated from the 3H4 → 3H6 transition of Tm3+ with the ratio of NIR emission, and a blue band up to 9,633 was obtained. Through detailed analysis of the crystal structure and the energy transfer between Tm3+ and Yb3+, it is elucidated that the host lattice with low phonon energy cooperative with the energy mismatch results in a dramatic population of the 3H4 state as well as ultrapure NIR-to-NIR single band emission. Moreover, up-conversion (UC) emission properties and the decay lifetimes of β-PbF2: Yb3+/Tm3+ in GCs were explored thoroughly. The results illustrate that efficient cross relaxation (CR) processes between Tm3+ generate the energy redistribution in UC emission spectra, further concentrating energy to NIR emission. These two issues can be treated as crucial factors on ultrapure NIR-to-NIR single band emission in β-PbF2: Yb3+/Tm3+ in GCs. The ultrapure NIR-to-NIR single band emission through 976 nm laser excitation is advantageous for enhancing resolution and has potential application in bio-imaging fields.
关键词： Energy mismatch,Fluoride nanocrystal doped with Tm3+,Glass ceramics,Single band,Cross relaxation
更新于2025-09-09 09:28:46
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Fabrication and characterizations of highly transparent Tb3Ga5O12 magneto-optical ceramics
摘要： Terbium gallium garnet (TGG) precursor was synthesized by the co-precipitation method from the mixed solution of terbium and gallium nitrates using ammonium hydrogen carbonate (AHC) as the precipitant. Fine and low-agglomerated TGG powders with the average particle size of 158 nm were obtained by calcining the precursor at 1100 °C for 4 h. Then, TGG transparent ceramics were successfully fabricated by a new two-step sintering method. The TGG ceramics pre-sintered at 1500 °C for 3 h in air and then HIP post-treated at 1550 °C for 3 h under 150 MPa argon gas showed the best optical quality and the in-line transmittance was 80.3% at 1064 nm. The Verdet constant of the TGG ceramic at 633 nm was about 136.8 rad T?1 m?1, which was rather close to that of the commercial TGG single crystal. High transparency and high Verdet constant make it an attractive alternative for the high-power Faraday isolators.
关键词： TGG,Transparent ceramics,Air pre-sintering,HIP post-treatment
更新于2025-09-09 09:28:46
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Phase structure analysis and pyroelectric energy harvesting performance of Ba(Hf <sub/><i>x</i> </sub> Ti <sub/> 1 <i>-x</i> </sub> )O <sub/>3</sub> ceramics
摘要： Ba(Ti1-xHfx)O3 ceramics were synthesized by a solid-state reaction process. The evolution of the phase structure was identified by XRD spectrum, dielectric spectroscopy and temperature-dependent Raman spectroscopy for the Ba(Ti1-xHfx)O3 ceramics. In addition, pyroelectric energy harvesting properties based on the Olsen cycle were investigated for the first time. A maximum pyroelectric energy harvesting density value of ND=491.30 kJ/m3 (ΔT=120 °C, EH=50 kV/cm) was achieved in the Ba(Hf0.05Ti0.95)O3 ceramic. Compared with those of BT, the values of ND more than doubled in the temperature range from ΔT=60 °C to ΔT=100 °C in the Ba(Hf0.05Ti0.95)O3 ceramic and even increased 3.2 times at ΔT=80 °C near the Curie temperature (TC) of the Ba(Hf0.05Ti0.95)O3 sample. In addition, a larger pyroelectric energy harvesting density value of ND=367.10 kJ/m3 (ΔT=120 °C, EH=50 kV/cm) was acquired in the Ba(Hf0.12Ti0.88)O3 ceramic. Values of ND-BHT5/ND-BT and ND-BHT12/ND-BT were analyzed in the Ba(Ti1-xHfx)O3 ceramics. The optimal pyroelectric properties can be obtained in the vicinity of the ferroelectric to paraelectric phase-transition region.
关键词： Phase transition,Lead-free ceramics,Raman spectra,Ferroelectric materials,Energy harvesting
更新于2025-09-09 09:28:46
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Nanostructured Titania Templated by Natural Cellulose Substance: Effect of Vanadium-Doping on the Anatase-to-Rutile Phase Transformation
摘要： Vanadium-doped rutile titania nanomaterial was synthesized by calcination of titania/vanadia composite thin gel films pre-coated natural cellulose substance (e.g., ordinary filter paper) at a relatively low temperature (600 °C). A better mixture of titanium and vanadium species is achieved during the layer-by-layer (LbL) deposition process with cellulose nanofiber as a template, leading to more vanadium dopants incorporated in the titania crystal lattices. By sufficient vanadium-doping, the phase transformation temperature from anatase to rutile phase of titania is decreased effectively. The doping mode and existing state of vanadium in the titania nanomaterials and the effect on the anatase-to-rutile phase transformation have been studied. This strategy provides a facile and effective route to facilitate the phase transformation of various nanostructured metal oxides templated by natural cellulose substance through doping appropriate functional metal ions in the LbL deposition process.
关键词： Biomimetic,Ceramics,Sol–Gel Preparation,Phase Transformation,Titania
更新于2025-09-04 15:30:14
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Influence of compositional ratio K/Na on structure and piezoelectric properties in [(Na1?xKx)0.5Bi0.5]Ti0.985Ta0.015O3 ceramics
摘要： [(Na1-xKx)0.5Bi0.5]Ti0.985Ta0.015O3 (abbreviated as Ta-NK100x) lead-free ceramics with good piezoelectric properties were prepared using a solid-state reaction method. The structure and electrical properties of Ta-NK100x had been systemically investigated. The highest bipolar strain of 0.458% and the unipolar strain 0.448% are achieved at x = 0.18 at 60 kV/cm. Meanwhile, the corresponding normalized strain d*33 reaches 747 pm/V. In addition, the unipolar strain of the poled Ta-NK18 increases to 0.537%, and corresponding d*33 increases slightly to 894.5 pm/V at 60 kV/cm. The electric-field-induced phase transition between ferroelectric and relaxor is found to play a dominant role in the origin of the large strain. Moreover, the strain behavior remains stable within 105 switching cycles which indicating the prepared ceramics are promising candidates for actuators and stress sensors.
关键词： ferroelectric,relaxor,solid-state reaction,piezoelectric properties,lead-free ceramics
更新于2025-09-04 15:30:14
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Structural, dielectric, and impedance study on ZnO doped Sr(Fe0.5Nb0.5)O3 ceramics
摘要： SrFe0.5Nb0.5O3 (SFN) ceramics doped with ZnO were synthesized via a conventional mixed oxide technique. Phase formation investigation by X-ray diffraction technique (XRD) revealed that all ceramic samples exhibited pure perovskite phase. Grain size as observed by an electron microscopy (SEM), was found to decrease with increasing the additive concentration. Dielectric properties and other related properties of the ceramics were also investigated. Very high dielectric constants > 3.3×105 (at temperature 250 °C and 1 kHz) were found for the 3 vol% doped samples. The impedance spectroscopy analysis suggested that the dielectric behavior of the samples could be linked with the Maxwell - Wagner polarization mechanism.
关键词： Perovskite,High dielectric constant,Ceramics,Maxwell - Wagner polarization,Impedance spectroscopy,SrFe0.5Nb0.5O3
更新于2025-09-04 15:30:14
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High Pressure effect on fluorescence lifetime <i>τ</i> for magnetic dipole <sup>5</sup> D <sub/>0</sub> → <sup>5</sup> F <sub/>1</sub> transitions in YAG:Eu <sup>3+</sup>
摘要： The fluorescence lifetime for magnetic dipole 5D0→7F1 transition in yttrium aluminum garnet doped with Eu3+ (YAG:Eu3+) crystal was studied under the pressure of up to 10.4 GPa at room temperature. The fluorescence lifetime τ (5D0→7F1 transition) slowly decreased with pressure. The pressure effect on τ (5D0→7F1 transition) was explained with a model which considered pressure effect on line position: inter-ionic distance, ion volume, molecular volume, ion polarizability, molecular polarizability, sample refractive index, and surrounding hydrostatic medium refractive index. The fluorescence lifetime τ calculated by the presented model was in close correspondence with the experimental values.
关键词： rare earth,fluorescence lifetime,YAG:Eu3+,optical properties,glass ceramics,High pressure
更新于2025-09-04 15:30:14