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Enhanced near-infrared emission in Yb3+-Cr3+ codoped KZnF3 glass ceramics excited by a solar simulator
摘要： Cr3+-Yb3+ codoped bulk glass-ceramics containing KZnF3 nanocrystals are fabricated by thermal treatment of cast glass samples and characterized by X-ray diffraction and transmission electron microscopy. The luminescent properties of the glass and glass ceramic are investigated from the measured photoluminescence spectra and fluorescent lifetime. The measurement results demonstrate that Cr3+ and Yb3+ ions are both predominantly hosted in the KZnF3 nanocrystals, and the energy absorbed by Cr3+ ions is efficiently transferred to Yb3+ ions when excited at 450 nm. Compared to the glass, the near-infrared emission in the Cr3+-Yb3+ codoped glass ceramics is significantly enhanced when the excitation wavelength lies in the range λ~400–800 nm of a solar simulator. Results indicate that the Cr3+-Yb3+ codoped KZnF3 glass ceramic provides a promising material for spectral conversion from visible sunlight to near-infrared emission and a novel gain material for solar pumped fiber laser.
关键词： Nanocrystal,Solar pumped,Glass ceramics,Near-infrared
更新于2025-09-23 15:23:52
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Investigation on tool wear process of milling wave-transmitting Si <sub/>3</sub> N <sub/>4</sub> ceramics
摘要： Due to the low fracture toughness of wave-transmitting Si3N4 ceramics, the special material removal mechanism causes the tool wear to be different. The paper presents the tool wear forms and mechanism under different milling depth. The effect of tool wear on cutting force and machined surface morphology is discussed. Tests have been performed under typical conditions of cutting depth of 0.3 mm (in plastic-domain processing) and 0.4 mm (in brittle-domain processing). The results show that the abrasive wear caused by the chips is the main mechanism of the cutting edge wear and the flank wear, the increase of the side edge rear angle with tool wear is the main cause of the chipping phenomenon. The cutting depth is a significant influence parameter to the wear characteristics, and two types have been distinguished. As the material removal volume ascending, the cutting edge wear and the flank face wear has a stable period, and the root-mean-square deviation of processing surface increases to 1.6 μm, while that increase with the material removal volume continuously, and the processing surface decreases to 1.4 μm. It has been proved that the cutting force tends to increase first and then decrease as the material removal volume is about 4320 mm3.
关键词： ceramics,milling,morphology,plastic-domain,chipps,wear,Tool,brittle-domain,surface
更新于2025-09-23 15:23:52
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The sintering behavior and physical properties of Li <sub/>2</sub> CO <sub/>3</sub> -doped Bi <sub/>0.5</sub> (Na <sub/>0.8</sub> K <sub/>0.2</sub> ) <sub/>0.5</sub> TiO <sub/>3</sub> lead-free ceramics
摘要： In this study, Li2CO3-doped Bi0.5(Na0.8K0.2)0.5TiO3 (BNKT) ceramics were fabricated via the conventional solid-state reaction using ultrasound waves for preliminary milling. The milling time was shortened from 20 h to 1 h with ball milling. The phase structure of BNKT investigated by X-ray diffraction showed a single perovskite phase. With increasing Li2CO3 content, the phase structure of the ceramics changed from rhombohedral to tetragonal. At a sintering temperature of 1 100 8C and Li2CO3 content of 0.4 wt.%, the best physical properties of the ceramics, such as density (q), 5.9 g cm–3; electromechanical coupling factors (kp), 0.32; (kt), 0.29; remanent polarization (Pr), 12.0 lC cm–2; dielectric constant (er), 1 191; and highest dielectric constant (emax), 5 800, were obtained.
关键词： Lead-free ceramics,Electromechanical coupling factor,BNKT,Sintering temperature,Dielectric constant
更新于2025-09-23 15:23:52
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Effect of processing conditions on (Ba1-xCax)(Ti0.9Sn0.1)O3 lead-free ceramics for the enhancement of structural, humidity sensing and dielectric properties
摘要： The present study reports detailed guidelines for the preparation of high-quality perovskite (Ba1-xCax)(Ti0.9Sn0.1)O3 (BCTS) (x = 0.0–0.1) lead-free ceramics by solid state reaction. The compositions (x = 0.0–0.04) exhibit orthorhombic–tetragonal phase transition (TO-T), except x ≥ 0.06 that shows a pure tetragonal structure phase which conformed by X-ray diffraction (XRD). The microstructure and purity of the sintered ceramics were examined using scanning electron microscope equipped with an energy dispersive spectrometer (SEM-EDS). Some pores existing in the grain boundary were observed at high concentrations of Ca content. Field emission scanning electron microscope (FE-SEM) was used to examine the morphology of sensing film of the calcined powder and it was prepared as a humidity sensor using screen-printing technique. All the compositions exhibited poor sensitivity toward the humidity sensing in the range of 0–98% RH at room temperature. Hot-stage microscope (HSM) has been used to investigate the sintering curve of the pure calcined powder and it was found that the suitable sintering temperature for obtaining a fully dense microstructure is 1400 °C. The highest values of permittivity (εr = 46,515, at 10 kHz) and piezoelectric coefficient (d33 = 510 pC/N) were achieved in the composition x = 0.02. The difference between alumina and platinum crucibles for the processing of the powders has been introduced, and by the aid of dispersive spectrometer analysis and it was indicated that use of alumina crucibles leads to the undesired presence of Al in the ceramics, which can be prevented by using a capped platinum crucibles.
关键词： Lead-free ceramics,Humidity sensing,Phase formation,Processing,Dielectric properties
更新于2025-09-23 15:23:52
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In-situ synthesis of mullite-SiCw composite ceramics in Li2O-Al2O3-SiO2 ternary system for solar heat transmission pipeline
摘要： Nano-SiC whiskers (nano-SiCw) were in-situ synthesized in Li2O-Al2O3-SiO2 ternary system for preparing highly densified mullite-SiCw composite ceramics used for solar heat transmission pipeline. Mechanisms on the in-situ synthesis of nano-SiCw in the ternary system were investigated and the impact of nano-SiCw on the performances of the composites had been studied. Results showed that the growth processes of nano-SiC whiskers in Li2O-Al2O3-SiO2 ternary system were dominated by liquid-solid (LS) mechanism and the Li2CO3 additive could improve the SiCw yield through increasing the content of liquid phase and lowering the liquid viscosity. Sample BS3 (with 2.22 wt% Li2CO3 additive) sintered at 1440 °C obtained the highest SiC content of 47.9%. Nano-SiC whiskers with a diameter of 20e30 nm were interlocking with rod-like mullite crystals to improve the mechanical properties of the composites, and sample BS1 sintered at 1420 °C showed the highest bending strength of 115.4 MPa. The in-situ synthesized SiCw also shew significant effects on improving the thermophysical properties of the composites and sample BS1 exhibited a 3.6 times higher thermal conductivity than that of blank sample B1 without the introduction of nano-SiCw.
关键词： Li2O-Al2O3-SiO2 ternary system,Thermal conductivity,Mullite-SiCw composite ceramics,Solar heat transmission pipeline,SiC whiskers
更新于2025-09-23 15:23:52
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Fabrication and electromagnetic wave absorption property of quartz ceramics with a gradient distribution of BaTiO3
摘要： Quartz ceramics with a uniform/gradient distribution of BaTiO3 (U/G–SO–BTO) are fabricated by cold pressing a powder blend with BTO followed by sintering and using a combined technique of spreading the powder blends with gradually increased BTO layer–by–layer and sintering. The electromagnetic wave absorption properties of these two ceramics are studied in detail. For U–SO–BTO samples, the primary electromagnetic re?ection is strong due to the aggravated impedance mismatch at their surfaces. The electromagnetic wave re?ectivity of U–SO–BTO could only reach ?7.0 dB when the sample thickness is 6 mm and the BTO content is 8.0 wt%, and it decreases slightly to ?8.1 dB when the sample thickness is increased to 10.0 mm and the BTO content is decreased to 5.0 wt% simultaneously. For G–SO–BTO samples, electromagnetic waves could enter with little re?ection due to the weak surface impedance mismatch, and the electromagnetic waves entering these samples could propagate forward while being absorbed gradually with little re?ection because of the weak impedance mismatch at the interfaces. The G–SO–BTO samples are promising excellent electromagnetic absorbing materials because their electromagnetic wave re?ectivity could reach a level lower than ?12.0 dB and could decrease further from –12.2 to ?13.1 dB as the layer thickness increases from 1.0 to 2.0 mm.
关键词： Impedance mismatch,Electromagnetic wave absorption,Quartz ceramics,Electromagnetic re?ection,Gradient distribution,BaTiO3
更新于2025-09-23 15:22:29
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Preparation and scintillation properties of Eu2+:CaF2 scintillation ceramics
摘要： Different concentration of Eu2+ -doped CaF2 ceramics, designed to the low (0.01 at% and 0.04 at%) and the high (0.2 at% and 0.5 at%), have been prepared by hot-press sintering method. Under 355 nm laser excitation, all the ceramics showed emission bands at 425 nm due to 5d-4f transitions of Eu2+ ions and weak emission peaks at 574, 617 and 630 nm due to the 4-4f transitions of Eu3+ ions. Under X-rays irradiation, the emission bands at 315 nm and 422 nm, ascribed STE and 5d-4f transitions of Eu2+ ions, were observed and the weak emission peaks, ascribed 4f‐4f transitions of Eu3+ ions, were also observed in all the samples. Furthermore, the scintillation decay lifetime and pulse height spectra of the samples were investigated.
关键词： Photoluminescence,Eu2+:CaF2 ceramics,Radioluminescence,Scintillation
更新于2025-09-23 15:22:29
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Lead-free Ag <sub/> 1-3 <i>x</i> </sub> La <sub/><i>x</i> </sub> NbO <sub/>3</sub> Antiferroelectric Ceramics with High Energy Storage Density and Efficiency
摘要： Environmentally benign lead-free bulk ceramics with high recoverable energy density (Wrec) are very attractive in advanced pulsed power capacitors. In this work, composition engineering was adopted by La3+ modification to improve the energy storage performance of Ag1-3xLaxNbO3 ceramics. It was found the antiferroelectric (AFE) phase was stabilized after La3+ substitution, as a result of the reduced tolerance factor t. Significant improvement of Wrec and energy storage efficiency (η) were achieved with value of 3.12 J/cm3 and 0.63 for x=0.02 at an electric field of 230 kV/cm, more than 1.5 times the value of pure AgNbO3 (Wrec=1.9 J/cm3, η=0.40). The excellent energy storage properties are resulted from the increased antiferroelectric-ferroelectric phase transition electric field (EF), ferroelectric-antiferroelectric phase transition electric field (EA) and breakdown electric field (Eb). The enhanced Eb was ascribed to the decreased grain size and increased electrical resistivity upon La3+ modification. The feature makes Ag1-3xLaxNbO3 a potential candidate for energy storage applications.
关键词： energy storage,ferroelectricity/ferroelectric materials,lead-free ceramics,dielectric materials/properties
更新于2025-09-23 15:22:29
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Quartz-containing glass-ceramics in the SiO <sub/>2</sub> -Li <sub/>2</sub> O-K <sub/>2</sub> O-MgO-CaO-Al <sub/>2</sub> O <sub/>3</sub> -P <sub/>2</sub> O <sub/>5</sub> system
摘要： Volume crystallization of quartz, triggered by adding P2O5, was investigated in the multicomponent SiO2–Li2O–K2O–MgO–CaO–Al2O3–P2O5 glass system. Glass‐ceramics comprising quartz as the main crystal phase besides lithium disilicate (Li2Si2O5) as a minor crystal phase were produced by controlled crystallization from the parent glass. According to quantitative crystal phase analysis by means of Rietveld refinement the mass fraction of the minor Li2Si2O5 phase decreased with increasing P2O5 content, while the fraction of quartz increased. Scanning electron microscopy revealed lath‐like Li2Si2O5 embedded in a matrix of rather globular quartz crystals forming an interlocking microstructure. Well machinable glass‐ceramics with a mean biaxial flexural strength of about 300 MPa and a fracture toughness of about 2.0 MPa × m0.5 could be realized. With mean values ≥13.6 × 10?6 K?1 the glass‐ceramics coefficient of thermal expansion is close to the one reported for low‐quartz crystals. The ease of production based on conventional glass melting and fabrication technology together with the good mechanical, optical, and machining properties enables the application of these materials in prosthodontics.
关键词： nucleation,lithium disilicate,low-quartz,glass-ceramics,quartz
更新于2025-09-23 15:22:29
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Defect formation in AlN after irradiation with He2+ ions
摘要： The paper presents results of studies on defect formation processes, radiation resistance, amd changes in the conductive and insulating characteristics of AlN ceramics under irradiation with 40 keV He2+ ions. The radiation fluence ranged from 1015 to 5x1017 ion/cm2. Using the method of X-ray structural analysis, it has been established that an increase in the irradiation fluence leads to a decrease in intensities of diffraction peaks and a change in lines shape, which indicates an increase in the concentration of distortions and stresses in the crystal structure. The change in concentration of deformation in the structure is due to the increase in the content of introduced helium and the formation of cascades of secondary defects and vacancies. At large fluences of irradiation (above 1017 ions/cm2), diffraction patterns show the formation of a halo characteristic of X-ray amorphous or highly disordered impurity inclusions and the formation of spherical inclusions in the surface layer, the average size of which varies from 50 to 100 nm. The decrease in resistance and thermal conductivity as a result of irradiation and the formation of helium inclusions in the structure indicates a degradation of the structural characteristics, as well as a decrease in radiation resistance, which is caused by a drop in strength characteristics.
关键词： ceramics,swelling,radiation embrittlement,defects,structural materials
更新于2025-09-23 15:22:29